Alcohol Flashcards

1
Q

Alc functional grp

A

R—OH

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2
Q

Alc classification

A
# R bonded to the C w/ OH grp
# OH grp
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3
Q

R bonded to the C w/ OH grp

A

Primary
Secondary
Tertiary

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4
Q

OH grp

A

Monohydric
Dihydric
Polyhydric

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5
Q

Nomenclature of Alc

A

Common names
Derived names frm CARBINOL
IUPAC

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6
Q

Common names often used

A

Name of Alkyl grp + Alc

CH3OH: Methyl Alc

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7
Q

Derived names frm CARBINOL eg

A

CH3CH2OH: Methyl carbinol

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8
Q

Carbinol

A

Old name of Methanol

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9
Q

IUPAC Rules

A

Parent chain has -OH
-OH given to the lower #
Name ending in -OL

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10
Q

CH3CH2CH2OH

A

Common: n propyl alc
Derived: ethyl carbinol
IUPAC: 1-propanol

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11
Q

CH3CHCH3OH

A

Common: isopropanyl alc
Derived: dimethyl carbinol
IUPAC: 2 propanol

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12
Q

Oxadation rgt

A

K2Cr2O7

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13
Q

Primary alc

A

Aldehyde

Carboxylic acid

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14
Q

Secondary alc

A

Ketone

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15
Q

Lucas Rgt

A

Zinc: catalyst

conc. HCl: reactant

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16
Q

Involves double replacement

A

Lucas Test

17
Q

Most reactive in Lucas Test

A

Tertiary alc

18
Q

No rxn in Oxidation test

A

Tertiary alc

19
Q

Don’t undergo rxn easily in Lucas Test

Needs heat

A

Primary alc

20
Q

Lucas test result

A

2 immiscible layers

21
Q

Usually undergone by methanol & ethanol

A

Dehydration

22
Q

OH grp bonds

A

Ion-dipole

H bonds

23
Q

Enhance water solubility

A

OH grp

24
Q

Esterified to form products

A

Alc

25
Q

Alc processes

A

Metabolism
Oxidation
Glucuronide/sulfate conjugation