AI - Nitrogen Chemistry Flashcards
What periodic group is Nitrogen in?
Group 5
Describe the bonding and lone pairs in Ammonia
3 covalent bonds between Nitrogen and hydrogen and a lone pair of electronsq
Describe the bonding and lone pairs in Ammonium ions
3 covalent bonds between Nitrogen and Hydrogen and a dative covalent bond from the Nitrogen to a 4th Hydrogen
Explain how Ammonia can act as a ligand
Its lone electron pair can form dative covalent bonds, allowing it to form complex ions with transition metal ions
Give the formula, systematic name and colour of 3 different oxides of nitrogen and any other names associated with them
1) NO - Nitrogen (II) oxide, (Nitrogen monoxide, Nitric oxide) - Colourless gas
2) N₂O - Nitrogen (I) oxide, (Dinitrogen monoxide, nitrous oxide) - Sweet smelling, colourless gas
3) NO₂ - Nitrogen (IV) oxide, (Nitrogen dioxide) - Brown gas with a sharp odour and toxic
What is the formula and oxidation state of nitrogen in the air and what produces this form of nitrogen?
N₂ (g)
0
Denitrifying bacteria
What is the formula and oxidation state of nitrogen in Ammonium ions in the soil and what produces this form of nitrogen?
NH₄⁺
-3
Bacteria and micro-organisms in the soil
What is the formula and oxidation state of nitrogen in Nitrate (V) ions in the soil and what produces this form of nitrogen?
NO₃⁻
+5
Nitrifying bacteria in the soil & bacteria in root nodules
What is the formula and oxidation state of nitrogen in Nitrate (III) ions in the soil and what produces this form of nitrogen?
NO₂⁻
+3
Nitrifying bacteria in the soil & bacteria in root nodules
What is the formula and oxidation state of nitrogen in Nitrogen (II) oxide and what produces this form of nitrogen?
NO
+2
Thunderstorms, car engines, denitrifying bacteria in soil
What is the formula and oxidation state of nitrogen in Nitrogen (IV) and what produces this form of nitrogen?
NO₂
+4
Oxidation of NO in atmoshpere
What is the formula and oxidation state of nitrogen in Nitrogen (I) oxide and what produces this form of nitrogen?
N₂O
+1
Denitrifying bacteria in the soil
What processes converts Nitrogen gas in the air into nitrogen oxides
Lightning and burning fossil fuels
What processes convert Nitrogen gas in the air into Ammonia (NH₃)
Nitrogen-fixing bacteria and the Haber process
Give the process in which Ammonium ions enter the soil due to animals
Excretion, death and decay