AI - Nitrogen Chemistry Flashcards

1
Q

What periodic group is Nitrogen in?

A

Group 5

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2
Q

Describe the bonding and lone pairs in Ammonia

A

3 covalent bonds between Nitrogen and hydrogen and a lone pair of electronsq

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3
Q

Describe the bonding and lone pairs in Ammonium ions

A

3 covalent bonds between Nitrogen and Hydrogen and a dative covalent bond from the Nitrogen to a 4th Hydrogen

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4
Q

Explain how Ammonia can act as a ligand

A

Its lone electron pair can form dative covalent bonds, allowing it to form complex ions with transition metal ions

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5
Q

Give the formula, systematic name and colour of 3 different oxides of nitrogen and any other names associated with them

A

1) NO - Nitrogen (II) oxide, (Nitrogen monoxide, Nitric oxide) - Colourless gas
2) N₂O - Nitrogen (I) oxide, (Dinitrogen monoxide, nitrous oxide) - Sweet smelling, colourless gas
3) NO₂ - Nitrogen (IV) oxide, (Nitrogen dioxide) - Brown gas with a sharp odour and toxic

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6
Q

What is the formula and oxidation state of nitrogen in the air and what produces this form of nitrogen?

A

N₂ (g)
0
Denitrifying bacteria

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7
Q

What is the formula and oxidation state of nitrogen in Ammonium ions in the soil and what produces this form of nitrogen?

A

NH₄⁺
-3
Bacteria and micro-organisms in the soil

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8
Q

What is the formula and oxidation state of nitrogen in Nitrate (V) ions in the soil and what produces this form of nitrogen?

A

NO₃⁻
+5
Nitrifying bacteria in the soil & bacteria in root nodules

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9
Q

What is the formula and oxidation state of nitrogen in Nitrate (III) ions in the soil and what produces this form of nitrogen?

A

NO₂⁻
+3
Nitrifying bacteria in the soil & bacteria in root nodules

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10
Q

What is the formula and oxidation state of nitrogen in Nitrogen (II) oxide and what produces this form of nitrogen?

A

NO
+2
Thunderstorms, car engines, denitrifying bacteria in soil

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11
Q

What is the formula and oxidation state of nitrogen in Nitrogen (IV) and what produces this form of nitrogen?

A

NO₂
+4
Oxidation of NO in atmoshpere

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12
Q

What is the formula and oxidation state of nitrogen in Nitrogen (I) oxide and what produces this form of nitrogen?

A

N₂O
+1
Denitrifying bacteria in the soil

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13
Q

What processes converts Nitrogen gas in the air into nitrogen oxides

A

Lightning and burning fossil fuels

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14
Q

What processes convert Nitrogen gas in the air into Ammonia (NH₃)

A

Nitrogen-fixing bacteria and the Haber process

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15
Q

Give the process in which Ammonium ions enter the soil due to animals

A

Excretion, death and decay

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16
Q

Give the processes of the conversion of Ammonium ions to Nitrate (V) ions

A

NH₄⁺ is converted to NO₂⁻ which in turn is converted to NO₃⁻ by denitrification

17
Q

Give the process in which Nitrate (V) ion is converted to Nitrogen gas in the air

A

Denitrification