admixtures Flashcards

1
Q

____ are ingredients other than portland cement, water, and aggregates that may be added to concrete to impart a specific quality to either the plastic (fresh) mix or the hardened concrete (ASTM C494).

A

admixtures

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2
Q

____ admixtures are charged into the mix as solutions.

A

some

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3
Q

Admixtures are classified by the following chemical and functional physical characteristics: ____

A
  1. air entrainers
  2. water reducers
  3. retarders
  4. hydration controller admixtures
  5. accelerators
  6. specialty admixtures
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4
Q

PCA stands for: ____

A

portland cement association

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5
Q

The Portland Cement Association (PCA) identifies four major reasons for using admixtures: ____

A
  1. to reduce the cost of concrete construction
  2. to achieve certain properties in concrete more effectively than by other means
  3. to ensure quality of concrete during the stages of mixing, transporting, placing, and curing in adverse weather conditions
  4. to overcome certain emergencies during concrete operations
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6
Q

_____ produce tiny air bubbles in the hardened concrete to provide space for water to expand upon freezing.

A

air entrainers

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7
Q

As moisture within the concrete pore structure freezes, three mechanisms contribute to the development of internal stresses in the concrete: ____

A

critical saturation, hydraulic pressure, osmotic pressure

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8
Q

Upon freezing, water expands in volume by 9%.

A

critical saturation

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9
Q

Freezing water draws unfrozen water to it.

A

hydraulic pressure

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10
Q

Water moves from the gel to capillaries to satisfy thermodynamic equilibrium and equalize alkali concentrations.

A

osmotic pressure

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11
Q

_____ permit water to flow from the interlayer hydration space and capillaries into the air voids, where it has room to freeze without damaging the parts.

A

osmotic pressure

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12
Q

_____ reduce the durability of hardened concrete, especially when cycles of freeze and thaw are repeated many times.

A

internal stresses

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13
Q

_____ is recommended for all concrete exposed to freezing.

A

air entrainment

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14
Q

Entrained air voids have diameters that range from ____, with the majority being less than 0.1 mm.

A

0.01 to 1 mm

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15
Q

____ improves with decreasing void size, and small voids reduce strength less than large ones.

A

frost resistance

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16
Q

The fineness of air voids is measured by the ______, equal to the total surface area of voids in a unit volume of paste.

A

specific surface index

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17
Q

_____ improves concrete’s resistance to several destructive factor, including freeze-thaw cycles, deicers and salts, sulfates, and alkali-silica reactivity.

A

air entrainment

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18
Q

____ also increases the workability of fresh concrete.

A

air entrainment

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19
Q

High strength if ___ to attain with air-entrained concrete.

A

difficult

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20
Q

Air entrainers are usually ____ and should meet the specification of ASTM C260.

A

liquid

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21
Q

The agents enhance air entrainment by ____ the surface tension of the mixing water.

A

lowering

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22
Q

____ of fresh or plastic concrete requires more water than is needed for hydration.

A

workability

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23
Q

The excess water, beyond the hydration requirement, is detrimental to all desirable properties of hardened concrete. Therefore, ______ have been developed to gain workability and, at the same time, maintain quality.

A

water-reducing admixtures

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24
Q

____ increase the mobility of the cement particles in the plastic miz, allowing workability to be achieved at lower water contents.

A

water reducers

25
Q

Water reducers are produced with different levels of effectiveness: ____

A

conventional, mid-range, high-range

26
Q

The high-range water reducer is typically called ______

A

plasticizer or superplasticizer

27
Q

____ can be used to indirectly to gain strength.

A

water reducing admixtures

28
Q

Hewlett (1988) demonstrated that water reducers can actually be used to accomplish three different objectives: ___

A
  1. adding a water reducer without altering the other quantities in the mix increases the slump
  2. the strength of the mix can be increased by using the water reducer by lowering the quantity of water and keeping the cement content constant
  3. the cost of the mix, which is primarily determined by the amount of cement, can be reduced. the amount of cement is then reduced to keep the water-cement ration equal to the original mix
29
Q

A ____ allows the use of a lower amount of mixing water while maintaining the same workability level.

A

water reducer

30
Q

______, or high-range water reducers, can either greatly increase the flow of the fresh concrete or reduce the amount of water required for a given consistency.

A

superplasticizers (plasticizers)

31
Q

Superplasticizers can be used when:

A
  1. a low water-cement ratio is beneficial
  2. placing thin sections
  3. placing concrete around tightly spaced reinforcing steel
  4. placing cement underwater
  5. placing concrete by pumping
  6. consolidating the concrete is difficult
32
Q

When superplasticizers are used, the fresh concrete stays workable for a short time, _____ minutes, and is followed by rapid loss in workability.

A

30-60

33
Q

Some construction conditions require that the time between mixing and placing or finishing the concrete be increased. In such cases, ____ can be used to delay the initial set of concrete.

A

retarders

34
Q

Retarders are used for several reasons, such as the following: ___

A
  1. offsetting the effect of hot weather
  2. allowing for unusual placement or long haul distances
  3. providing time for special finishes
35
Q

_____ can reduce the strength of concrete at early ages (1 to 3 days).

A

retarders

36
Q

These admixtures have the ability to stop and reactivate the hydration process of concrete.

A

hydration-control admixtures

37
Q

Hydration-control admixtures consists of two parts: ____

A

stabilizer, activator

38
Q

Adding the ____ completely stops the hydration of the cementing materials for up to 72 hours.

A

stabilzer

39
Q

Adding the ______ to the stabilizes concrete reestablishes normal hydration and setting.

A

activator

40
Q

These admixtures are very useful in extending the use of ready-mixed concrete when the work at the job site is stopped for various reasons.

A

hydration-control admixtures

41
Q

____ are used to develop early strength of concrete at a faster rate than that developed in normal concrete.

A

accelerators

42
Q

Accelerators are used to:

A
  1. increases rate of strength gain
  2. reduce the amount of time before finishing operations begin
  3. reduce curing time
  4. plug leaks under hydraulic pressure efficiently
43
Q

_____ is the most widely used accelerator (ASTM D98).

A

calcium chloride, CaCl2

44
Q

Concrete with CaCl2, develops ______ compared with plain concrete cured at the same temperature.

A

higher early strength

45
Q

The PCA recommends against using calcium chloride under the following conditions: ____

A
  1. concrete is prestressed
  2. concrete contains embedded aluminum such as conduits, especially if the aluminum is in contact with steel
  3. concrete is subjected to alkali-aggreagate reaction
  4. concrete is in contact with water or soils containing sulfates
  5. concrete is placed during hot weather
  6. mass application of concrete
46
Q

Several alternatives to the use of calcium chloride are available: _____

A
  1. using high early strength (Type III) cement
  2. increasing cement content
  3. curing at higher temperatures
  4. using non-calcium chloride accelerators such as triethanolamine, sodium thiocyanate, calcium formate, or calcium nitrate
47
Q

What are examples of specialty admixtures?

A

workability retaining
corrosion inhibitors
damp-proofing agents
permeability-reducing agents
fungicidal, germicidal, and insecticidal admixtures
pumping aids
bonding aids
grouting agents
gas-forming agents
coloring agents
shrinkage reducing

48
Q

Supplementary cementitious materials include: _____

A

fly ash, ground granulated blast furnace slag, silica fume, and natural pozzolans

49
Q

_____ is the most commonly used pozzolan in civil engineering structures.

A

fly ash

50
Q

____ is a by-product of the coal-fired electricity production.

A

fly ash

51
Q

Fly ash is classified (ASTM C618) as follows: ____

A

class N, class F, class C

52
Q

___ raw or calcined natural pozzolans, including diatomaceous earths, opaline cherts and shales, ruffs and volcanic ashes or pumicites, and some calcined clays and shales.

A

class N

53
Q

____ fly ash with pozzolan properties.

A

class F

54
Q

____ fly ash with pozzolan and cementitious properties.

A

class C

55
Q

Fly ash ____ the workability of the fresh concrete.

A

increases

56
Q

_____ is made from iron blast furnace slag. It nonmetallic hydraulic cement consisting basically of silicates and aluminosilicates of calcium, which is developed in a molten condition simultaneously with iron in a blast furnace.

A

slag cement

57
Q

____ is a by-product of the production of silicon metal or ferrosilicon alloys.

A

silica fume

58
Q

A ____ is a siliceous and aluminous material which, in itself, possesses little or no cementitious value but will, in finely divided form and in the presence moisture, react chemically with calcium hydroxide at ordinary temperatures to form compounds possessing cementitious properties (ASTM C595).

A

natural pozzolans