Addition Of Alkenes Flashcards
Test for unsaturation
• Use bromine water
• Bromine adds across double bond
• Solution colourless
• So Alkene
What does polymer show
Long chain of alkene with C-C not C=C
What does monomer show
• Shows repeating part of alkane with C=C
~ no bracket just n on right
Repeating unit
•One section of alkene
• No double bond
• Bracket
Property of long chain alkene
•Larger number of C-H and C-C
•Non polar, strong, lots of vdw
•Difficult to break and unreactive
What is PVC and how to make it flexible
•Rigid polymer
~chains attracted by vdw
•PVC + plasticiser = flexible PVC
~ small molecules fit between polymer chains
~ make them move further apart
~intermolecular forces weaken
~ chains slide over each other
Uses of low density and high density polyethene
•HDPE
~ higher mp
~ low temp & pressure
~ regular parttern
~ crates, buckets, bottles
•LDPE
~ flexible & stretch
~ high temp & pressure
~ irregular pattern
~ plastic bags, electrical insulation
What is polymerisation
• joins identical monemers
• to make polymers
Physical properties of alkanes
• weak vdw
• as molecules increase, bp increases
•insoluble in water
•branching lowers pb as more SA