ACS Final Review Flashcards

1
Q

What determines atomic number? What does that mean?

A

Number of positively charged protons in the nucleus. Emission of any charged particle would change the atomic number.

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2
Q

Define paramagnetic

A

atoms with unpaired electrons

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3
Q

When n goes from 4 to 2 is energy being absorbed or released?

A

absorbed

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4
Q

When n goes from 2 to 3 is energy being absorbed or released?

A

released

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5
Q

Energy must be ________ by the atom for an electron to move from one energy state in an atom to another energy state that is more remote from the nucleus.

A

absorbed

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6
Q

Define Inert Gas

A

Noble Gas

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7
Q

A sodium ion differs from a sodium atom in that the sodium ion

A

has fewer electrons.

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8
Q

In effecting nuclear changes by bombarding target nuclei with positively charged alpha particles, it is necessary to accelerate these particles to high speed because it is necessary to…
A) Drive the positive particles through the electron cloud
B) overcome the force of repulsion of the nucleus.
C) focus the bombarding particle more accurately.
D) strip electron from the atom.

A

B) overcome the force of repulsion of the nucleus

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9
Q

The existence of discrete (quantized) energy levels in an atom may be inferred from…

A

atomic line spectra

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10
Q

Helium has two electrons in the 1s orbital. When it becomes slightly ionized, forming He+,
A) its spectrum resembles that of the hydrogen spectrum
B) the remaining electron is easier to move
C) the nuclear charge has decreased by one
D) it has lost one atomic mass unit

A

A) its spectrum resembles that of the hydrogen spectrum

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11
Q

The structure of CO3^2- ion can be described in the Lewis formulation by these structures. This means that . . .
A) two carbon to oxygen bonds are single bonds; the third is a double bond
B) three independent forms of CO3^2- ion coexist in equilibrium
C) the electrons must be rapidly exchanging among the three forms
D) the CO3^2- ion exists only one form: an average of the three principal structures shown.

A

D) the CO3^2- ion exists only one form: an average of the three principal structures shown.

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12
Q

Which concept describes the formation of four equivalent, single, covalent bonds by carbon in its compounds that resemble methane, CH4?

A

Hybridization

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13
Q

Define hybridization:

A

a mixing of the native orbitals on a given atom to form special atomic orbitals for bonding.

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14
Q

Define coordinate covalent bonding:

A

a metal–ligand bond resulting from
the interaction of a Lewis base (the ligand) and a Lewis acid
(the metal ion).

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15
Q
The fact that Pt(NH3)2Cl2 exists in two different isomeric forms offers evidence that the geometry is 
A) octahedral
B) square planar
C) tetrahedral
D) trigonal planar
A

B) square planar

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16
Q

As purity of a substance decreases, melting point__________.

A

decreases

17
Q

Substances with a lower numerical value of vapor pressure have _____ tendency to change from liquid to gas.

A

little

18
Q

As vapor pressure decreases, heat of vaporization ______.

A

increases

19
Q

As vapor pressure decreases, boiling point ______.

A

increases

20
Q

As vapor pressure decreases, surface tension ______.

A

increases

21
Q

Define solution:

A

homogenous mixtures of two or more substances

22
Q

What factor affects the vapor pressure of a liquid?

A

temperature

23
Q

A gas or vapor may be liquefied only at temperatures . . .

A

at or below the critical temperature.

24
Q

A gas behaves like an ideal gas at ____ temperature and _____ pressure.

A

high temp, low pressure

25
Q
Which metal reacts with concentrated NaOH to produce hydrogen gas? 
A) aluminum 
B) copper
C) iron 
D) magnesium
A

A) aluminium

26
Q
Which of these gases can be most efficiently collected by the displacement of water? 
A) ammonia
B) carbon dioxide
C) oxygen
D) hydrogen chloride
A

C) oxygen