ACIDS, BASES AND SALTS 2B Flashcards

1
Q

Definition of an acid

A

Proton donor - releases H+ ions when in aqueous solution

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2
Q

Definition of a strong and weak acid

A

Strong is fully dissociated in solution

Weak is partially dissociated in solution

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3
Q

What is the link between strength of acids and the concentration of H+ ions?

A

The weaker the acid is, the lower proportion of the acid is dissociated, and so there is a lower concentration of H+ ions in the solution.

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4
Q

How is a strong acid generally written?

A

HA(aq) -> H(aq)+ + A(aq)-

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5
Q

How is a weak acid generally written?

A

HA(aq) EQUILIBRIUM ARROWS H(aq)+ + A(aq)-

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6
Q

Definition of a base

A

Proton acceptor

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7
Q

Name the types of bases and how they are bases

A

Metal hydroxides - accepts H+ to become water
Metal oxides - accepts H+ to become OH- (soluble oxide)
- accepts 2H+ to become water
Ammonia/amino compounds - N forms a dative bond with H+ ion

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8
Q

How can water act as a base?

A

H+ +H2O -> H3O+ (hydronium ion)

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9
Q

How can water act as an acid?

A

H2O -> OH- + H+

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10
Q

Definition of an alkali

A

Soluble base that releases OH- ions in water

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11
Q

Definition of a salt

A

Ionic compounds formed when the H+ ions in acids are replaced by metal ions or ammonium ions

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12
Q

Acid + Metal hydroxide

A

Salt + Water

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13
Q

Acid + Metal oxide

A

Salt + Water

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14
Q

Acid + Metal carbonate

A

Salt + Water + Carbon dioxide

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15
Q

Acid + reactive metal

A

Salt + Hydrogen

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16
Q

Why do ionic compounds have high melting and boiling points?

A

A lot of energy is needed to break the strong electrostatic forces of attraction between oppositely charged ions.

17
Q

Why do ionic compounds conduct electricity when molten or in aqueous solution?

A

When molten, ions are free to move as mobile charge carriers.

18
Q

Why do ionic compounds dissolve in polar solvents?

A

Polar molecules break down the lattice structure and surround the ions in solution. If the compound has larger charges, they are less soluble.

19
Q

Why are ionic compounds hard crystalline substances?

A

Made up of ions that are strongly attracted to each other by electrostatic forces

20
Q

Soluble or insoluble - K

21
Q

Soluble or insoluble - Na

22
Q

Soluble or insoluble - NH4+

23
Q

Soluble or insoluble - Halides

A

Soluble except when combined with Ag+,Pb2+,Hg+

24
Q

Soluble or insoluble - Nitrates

25
Soluble or insoluble - Sulfates
Soluble except when combined with Ag+,Pb2+,Ca2+,Sr2+,Ba2+
26
Soluble or insoluble - Carbonates
Insoluble except when combined with Na, K, NH4+
27
Soluble or insoluble - Oxides
Insoluble except when combined with Group 1 or NH4+
28
Soluble or insoluble - Phosphates
Insoluble except when combined with Group 1 or NH4+
29
Soluble or insoluble - Hydroxides
Insoluble except when combined with Group 1 or NH4+, Ca2+, Mg2+, Sr2+, Ba2+
30
Soluble or insoluble - Sulfides
Insoluble except when combined with Group 1 or NH4+
31
Soluble or insoluble - Chromates
Insoluble except when combined with Group 1 or NH4+, Ca2+, Mg2+
32
Acid + Metal hydrogen carbonate
Salt + Water + Carbon dioxide
33
Acid + Alkali
Salt + Water
34
Test for halides (including in isolation)
Add silver nitrate to unknown substance Cl ion = white precipitate Br ion = cream precipitate I ion = yellow precipitate In isolation add dilute ammonia solution -> precipitate dissolves then it's Cl ions Add conc. ammonia solution -> dissolves then it's Br ions Doesn't dissolve in either then it's I ions
35
What are the ions that don't change in a reaction called?
Spectator ions
36
What must ionic equations balance for?
Atoms and charge
37
Test for sulfates
Add Barium chloride and if a white precipitate forms then it's a sulfate
38
Test for carbonates
Add dilute nitric acid and there should be effervescence. | To prove this is CO2, bubble it through limewater and it will turn cloudy
39
Test for ammonium ions
Add sodium hydroxide solution and heat. Hold damp red litmus paper over it and it will turn blue if ammonium ions are present