Acids and Bases Flashcards

1
Q

Acids

A

have H+ ions in front. have low pH

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2
Q

Bases

A

Bases don’t have to HAVE OH. They should be able to PRODUCE OH- somehow: directly or indirectly. have high pH. a base is a substance that can remove a proton from an acid

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3
Q

Hydronium

A

h+ ions react very quickly with water to produce H3O which is hydronium

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4
Q

the “proton” that bases remove

A

h+ because H+ is basically one proton since Hydrogen only naturally has one electron and no neutrons.

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5
Q

strong base

A

drano, window cleaner and dish soap

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6
Q

strong acids

A

HCL, HBR, HI, HNO3, H2SO4, HCLO4

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7
Q

square brackets

A

automatically means concentration in mol/L.

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8
Q

to find concentration using pH

A

10^-pH.

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9
Q

Arrhenius acids and bases

A

an acid is a substance that produces H+ ions while dissolved in water while bases produce OH- ions while dissolved in water

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10
Q

Arrhenius theory proves that

A
  • acids increase the concentration of H+ in aqueous solution, while bases increase the concentration of OH- in aqueous solution
  • therefore, all acids must contain Hydrogen as a source of H+ while bases must contain an OH- group as a source of OH-
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11
Q

Arrhenius theory is useful is

A
  • you are looking at the ions that result when an acid or base undergoes a neutralization reaction to form an ionic compound and water
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12
Q

problems with arrhenius theory

A
  • H+ can’t exist alone in an aqueous solution
  • water is polar so the H+ from acids must interact with water (it produces Hydronium)
  • it can’t explain why ammonia and several other substances react with water to produce a base, not an acid despite not having an OH- group
  • can’t explain why salts containing carbonate ions have basic properties
  • can’t explain reactions that take place in non-polar organic solvents, only those in water
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13
Q

B-L theory

A

an acid is a substance from which a proton (H+) can be removed. a base is a substance that can remove a proton from an acid

  • acids must contain a hydrogen in formula (Arrhenius acids= BL acids)
  • any negative ion (not just OH) can be a BL base
  • water doesn’t have to be the only solvent
  • one substance must provide a proton and another substance must receive the same proton therefore an acid base reaction involved the transfer of a proton
  • any substance can be an acid as long as another substance behaves as a base
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14
Q

Conjugate acid base pairs (BL theory)

A

Acid: same chemical formula on other side of eqn but it has lost a hydrogen becoming the conjugate base
base: came chem formula on other side of eqn but it has gained a hydrogen therefore conjugate acid

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15
Q

strong and weak acids

A

strong ones ionize/disassociate completely in water. weak ones don’t do this completely

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16
Q

ionization vs. disassociation

A

ionization: process of forming an ion. acids ionize because they are molecular compounds
dissociation: process in which ions break apart when dissolved in solution. bases are ionic compounds so they disassociate

17
Q

pH scale

A

power of hydrogen. every unit is a scale of 10 ex 2 -7 is difference of 10^7

18
Q

hydronium and bL theory

A
  • only in this theory since they found out that H+ can’t exist by itself in water
19
Q

in any aqueous solution

A

both hydronium and hydroxide ions exist

20
Q

in pure water

A

hydronium = hydroxide with a pH and pOH of 7

21
Q

in acidic solutions

A

more hydronium than OH

22
Q

in basic solutions

A

more OH than H3O

23
Q

pH + pOH

A

= 14

24
Q

[H3O+][OH-]

A

1x 10^-14

25
Q

titration

A
  • To determine the concentration of a particular solute in a solution
  • This procedure involves combining a solution of unknown concentration with a reagent solution of known concentration, called a standard solution
26
Q

equivalence point

A

The point at which stoichiometrically equivalent quantities are brought together

27
Q

end point

A

the point of colour change (turns pink in basic solutions indicating that the neutralization reaction is complete) is called the end point