Acids and Bases Flashcards
Acids
have H+ ions in front. have low pH
Bases
Bases don’t have to HAVE OH. They should be able to PRODUCE OH- somehow: directly or indirectly. have high pH. a base is a substance that can remove a proton from an acid
Hydronium
h+ ions react very quickly with water to produce H3O which is hydronium
the “proton” that bases remove
h+ because H+ is basically one proton since Hydrogen only naturally has one electron and no neutrons.
strong base
drano, window cleaner and dish soap
strong acids
HCL, HBR, HI, HNO3, H2SO4, HCLO4
square brackets
automatically means concentration in mol/L.
to find concentration using pH
10^-pH.
Arrhenius acids and bases
an acid is a substance that produces H+ ions while dissolved in water while bases produce OH- ions while dissolved in water
Arrhenius theory proves that
- acids increase the concentration of H+ in aqueous solution, while bases increase the concentration of OH- in aqueous solution
- therefore, all acids must contain Hydrogen as a source of H+ while bases must contain an OH- group as a source of OH-
Arrhenius theory is useful is
- you are looking at the ions that result when an acid or base undergoes a neutralization reaction to form an ionic compound and water
problems with arrhenius theory
- H+ can’t exist alone in an aqueous solution
- water is polar so the H+ from acids must interact with water (it produces Hydronium)
- it can’t explain why ammonia and several other substances react with water to produce a base, not an acid despite not having an OH- group
- can’t explain why salts containing carbonate ions have basic properties
- can’t explain reactions that take place in non-polar organic solvents, only those in water
B-L theory
an acid is a substance from which a proton (H+) can be removed. a base is a substance that can remove a proton from an acid
- acids must contain a hydrogen in formula (Arrhenius acids= BL acids)
- any negative ion (not just OH) can be a BL base
- water doesn’t have to be the only solvent
- one substance must provide a proton and another substance must receive the same proton therefore an acid base reaction involved the transfer of a proton
- any substance can be an acid as long as another substance behaves as a base
Conjugate acid base pairs (BL theory)
Acid: same chemical formula on other side of eqn but it has lost a hydrogen becoming the conjugate base
base: came chem formula on other side of eqn but it has gained a hydrogen therefore conjugate acid
strong and weak acids
strong ones ionize/disassociate completely in water. weak ones don’t do this completely