ACIDS AND BASES Flashcards
Bronsted lowry acids and bases
acids are proton donors and bases are proton acceptors.
strong bases and strong acids
strong acids and strong bases are dissociated completely into aqueous solution.
reaction of acids and bases with water
are reversible. with acids a h30+ ions hydroxonium ions is produced and with bases hydroxide ions is produced.
weak acids and weak bases
weak acids and weak bases are dissociated slightly in an aqueous solution.
acid base reactions
when acids and bases react eith each other, protons are exchanged.
equilibrium in strong and weak acids
in strong acids, equilibrium lies well over to right and in weak acids, equilibrium lies well over to left.
note for finding ph in strong acids
concentration of strong acid is equal to concentration of h+ ions as the ions are dissociated completely in aqueous solutions.
monoprotic acids
monoprotic acids dissociate to produce one H+ ions for each acid molecule. eg is hcl and hno3
diprotic acids
diprotic acids dissociate to produce two h+ ions for each acid molecule. eg h2so4.
so conc is multiplied by 2.
Kw or ionic product of water
water exists in equilibrium with its ions. water dissociates into its ions very weakly. there is a very little concentration of h+ and oh_ ions that we assume the concentration of water to be constant.
Kw
Kw - [H+] [OH-]
UNIT OF KW IS MOL2 DM-6
imp points on ionic product of water
- value of kw is same in a solution at a given temperature.
- the value of kw changes when the temperature changes
- pure water has an equal concentration of h+ and oh - ions.
- sp kw of pure water can be [H+]2
equilibrium direction in strong acids and strong bases
forward reaction is favoured strongly as lots of H+ ions and OH- ions are produced.
equilibrium direction in weak acids and weak bases
backward reaction is favoured only little h+ and oh- ions are produced.
Ka or acid dissociation constant for weak acids
weak acids only dissociate slightly in aqueous solutions so we use this constant.