Acids, alkalis and salts Flashcards
What colour is:
Universal indicator
Neutral - green
Acid - Red
Alkali - Blue
What colour is:
Litmus
Acid-Red
Alkali - Blue
What colour is:
Methyl orange
Acid - red
Alkali - Yellow
Neutral - Orange
What colour is:
Phenolphthalein
Acid - colourless
Alkali - pink
What different groups are there in the pH scale:
0-3 strongly acidic - hydrochloric acid
4-6 weakly acidic - vinegar
7 - neutral - water
8-10 weakly alkaline - ammonia solution
11-14 - strongly alkaline - sodium hydroxide solution
is carbon dioxide acidic?
Yes, because it reacts in water to form carbonic acid
What are alkalis?
Soluble bases, as it needs to be dissolvable in water to be acidic/alkaline. These are also proton acceptors as they react with H+ to form H2O
What are the different equations for metals and acids?
Metal + acid -> salt + hydrogen
Metal oxide + acid -> Salt + water
Metal hydroxide + acid -> Salt + water
Metal carbonate + acid -> Salt + water + carbon dioxide
Ammonia + acid -> Salt (contains ammonium)
what is a neutralisation reaction?
When bases, e.g. metal oxides react with acids which neutralises to form water. OH+H=H2O
What is a titration?
When a neutralisation reaction occurs between bases and alkalis where the reactant’s volumes are measured
What are acids usually described as?
proton donors as they dissociate with a hydrogen ion which gives water a proton as H+ has just a proton
What are bases described as?
Proton acceptors as they react with H+ (a proton). e.g., hydroxide accepts H+ to form water
What are alkalis?
soluble bases that form OH- in water
How can it be determined if dilute acids react with a metal?
Depending on the position in the reactivity series. The reaction is more vigorous up the series.
Characteristics of strong and weak acids
Strong acid Weak acid
Nature Fully dissociated Partially dissociated
Examples Hydrochloric acid Ethanoic acid
Reaction with Mg Lots of bubbles, warm Some bubbles
Reaction with carbonates Bubbles Fewer bubbles
Colour of universal indicator with typical solution Red Orange -red
What are the different methods of forming soluble and insoluble salts
soluble salt from acid and alkali (titration)
soluble salt from an acid and insoluble base/metal/carbonate (crystallisation)
insoluble salt from two soluble salt (precipitation reaction)
Steps for making a soluble salt from an acid and an insoluble base
- add excess solid to the acid (to neutralise all the acid) and stir
- filter to remove excess solid when all acid has been neutralised
- Heat pure salt solution to evaporate some of the solution which concentrates the solution until some crystals form
- cool, leading to crystals forming (as at lower temperatures less solute can be dissolved in a solvent) and then filter to separate out the crystals
- Dry salts in warm oven
What are the steps for titration?
- add 25cm^3 of alkali/acid to a conical flask using a volumetric pipette. Add 4 drops of indicator
- use a burette to add acid/alkali till the first permanent colour change(swirl at the same time)
- Repeat the titration 3 times doing it drop by drop when the end point is approaching
- Do a titration without indicator adding the average volume of acid : alkali
- Heat pure salt solution to evaporate some of the solution which concentrates the solution until some crystals form
- cool, leading to crystals forming (as at lower temperatures less solute can be dissolved in a solvent) and then filter to separate out the crystals
- Dry salts in warm oven
Method for making an insoluble salt from 2 soluble parts
- combine equal quantities of two solutions and stir
- filter out the salt crystals (residue)
- wash crystals with pure distilled water
- dry salt crystals in warm oven
What is solubility measured as?
grams that will dissolve in 100 grams
of water at a specific temperature
what is the formula with moles, vol and conc
moles = vol * conc
what would be on the x and y axis of a solubility curve
y axis - g/100 g of water
x axis - temperature
How to find out:
volume of acid to neutralise an alkali
- add indicator in conical flask, as well as 25cm^3 of alkali with volumetric pipette and add in acid using a burette
- stop when colour change occurs (ideally name colour change)
- start value - end value gets change in volume
- do dropwise/swirling/repeating and using concordont results