Acids Flashcards
Define an acid
- as substance that produces hydrogen ions (H+) in aqueous soln
- hydrogen ions produced are responsible for the properties of the acids
Properties of acids
- sour taste
- dissolve in water to form soln that conducts electricity
- turns blue litmus paper red
- react with reactive metals (give up electrons easily to form cations) to form hydrogen gas and salt
- react with carbonates and hydrogen carbonates to form salt, water and CO2
- react with metal oxides and hydroxides to form salt and water
Property 4: Acids react with reactive metals to form hydrogen gas and salt
e. g. when a piece of magnesium ribbon added to dilute sulfuric acid, bubbles of hydrogen gas seen, magnesium sulfate is salt produced
- salts called sulfates when formed from sulfuric acid
- nitrates formed from nitric acid
- chlorides from hydrochloric acid
Which metals don’t react with acids?
- unreactive metals, below hydrogen in reactivity series
- e.g. copper or silver, if added to dilute acids, no reaction
- lead appears to not react with dilute hydrochloric acid and sulfuric acid
- initial reaction between lead and dilute acid produces layer of lead (II) sulfate
- layer is insoluble in water, quickly forms coating arnd metal, protects metal from further attack from acid
Property 5: react with carbonates and hydrogen carbonates to form salt, water, CO2
- CO2 can be tested by bubbling gas in limewater
- CO2 forms white precipitate (dont say cloudy) with limewater
- precipitate is insoluble solid particles produced in a liquid by chemical reactions
What is the role of water in acids?
- acids only display properties when dissolved in water
- acids produce hydrogen ions only in water
- hydrogen ions give acids their acidic properties
- piece of magnesium ribbon into sol of hydrogen chloride in water (aqueous hcl acid), bubbles of hydrogen produced (H+ ionised by aqueous hydrogen chloride, H+ allows acid to react with magnesium)
- if added to sol of hydrogen chloride in organic solvet, no water, no reaction (H+ not ionised, no reaction with magnesium)
Uses of acids: Sulfuric acid
- manufacture of fertilizers
- manufacture of detergents
- battery acid in cars
Sulfuric acid: manufacture of fertilizers
-impt starting material for production of ammonium sulfate and superphosphate (active ingredients in fertilisers)
Sulfuric acid: Manufacture of detergents
- converts hydrocarbons into organic acids
- organic acids then reacted with sodium hydroxide to produce the detergent
Sulfuric acid: Battery acid in cars
-reacts with lead plates to lead (IV) oxide plates in battery to generate electrical energy, used to keep engine running