acidity and basicity Flashcards
concept is based on whether the substance yields H+ or OH- in aqueous solutions
Arrhenius Acids and Bases
concept is based on the fact that acud-base reactions involve the transfer of H+ ions/proton from one substance to another
Bronsted-Lowry Acids and Bases
who donates and accepts proton?
Acid - donates
Base - accept
-Any species that has a hydrogen can potentially act as an acid.
-Any species that has a lone pair can potentially act as an base.
a substance capable of acting as either acid or a base is called
Amphiprotic
is a measure of the tendency of a compound to lose a proton
Acidity
is a measure of a compound’s affinity for a protn
Basicity
concept is based on the fact that acud-base reactions involve the transfer of electron pairs from one substance to another
Lewis Acids and Bases
subtances that have iunfilled valence orbitals
Lewis Acids
substances with a pair of nonbonding electrons
Lewis Bases
other term for lewis acids
Electrophiles
other term for lewis bases
Nucleophiles
results from the presence of bulky groups and congestion and twisting bonds
Steric Effect
shift in electron density through charge polarization transmitted through sigma bonds
Inductive Effect
affects availability of lone pair for protonation
Hybridization