Acid - Base Titrations Flashcards
What is volumetric analysis?
A process that uses the volume and concentration of one chemical reactant to determine the concentration of another unknown solution
It commonly involves titration.
What is the most commonly used technique in volumetric analysis?
Titration
What equipment is used to measure volumes in volumetric analysis?
Volumetric or graduated pipette and a burette
What must be prepared before performing a titration?
The standard solution
List key pieces of apparatus used in volumetric analysis.
- Beaker
- Burette
- Volumetric Pipette
- Conical Flask
- Volumetric Flask
What are volumetric solutions?
Solutions whose concentrations are known precisely
How should solutions be prepared to minimize measurement uncertainties?
Using three decimal place balances and volumetric flasks
What is the definition of concentration?
The amount of solute dissolved in a solvent to make 1 dm³ of solution
What is the solute in a solution?
The substance that dissolves in a solvent to form a solution
What is the solvent usually used in solutions?
Water
Define a concentrated solution.
A solution that has a high concentration of solute
Define a dilute solution.
A solution with a low concentration of solute
What are the three common ways to express concentration?
- Moles per unit volume
- Mass per unit volume
- Parts per million
What is the precision of burettes commonly marked to?
0.10 cm³
What is the uncertainty recorded for a burette reading?
±0.05 cm³
What is the equivalence point in a titration?
The point when the two solutions have reacted completely
What is used to indicate the end point of a titration?
An indicator
What is the purpose of placing a white tile under the conical flask during titration?
To make it easier to see the colour change
What is the typical volume measured with a volumetric pipette for titration?
Usually 20 or 25 cm³
What should be done as the titration approaches the end point?
Slow the flow of the burette and add the solution dropwise
What are concordant results?
Results that are within 0.1 cm³ of each other
How should initial and final burette readings be recorded?
To a precision of ±0.05 cm³
What is the titre in a titration?
The volume delivered, calculated and recorded to an uncertainty of ±0.10 cm³
How is percentage uncertainty calculated?
By comparing the significance of an absolute uncertainty on a measurement
True or False: Percentage error compares a result to a literature value.
True
What happens when adding or subtracting measurements?
Add together the absolute measurement uncertainties
What is the relationship between moles, concentration, and volume?
Number of moles (mol) = concentration (mol dm⁻³) x volume (dm³)
How do you calculate the mass of solute in a solution?
mass of solute (g) = number of moles (mol) x molar mass (g mol⁻¹)
colours of phenolphthalein
acid - colourless
alkali - pink
colours of methyl orange
acid - red
alkali - yellow
colours of universal indicator
acid - red
alkali - blue