AAMC FLASHCARDS
How is the order of a reaction determined?
The order of a reaction is determined by adding the exponents
so if this is the rate law equation is k = [A]m[B]n and you wanted it to be a second order reaction m and n could both equal 1 or one could equal 0 and the other 2 (in turn adding to 2)
What is the solubility product constant (Ksp)?
The solubility product constant is the equilibrium constant for a solid substance dissolving in an aquaous solution. It represents the level at which a solute dissolves in solution
If a solid is very soluble will the Ksp be high or low?
The more soluble a substance is, the higher the Ksp value
How do uncommon ions affect Ksp
Uncommon ions increase the Ksp value (uncommon ions are ions other than those involved in equilibrium)
What is the Ksp of this reaction:
aA(s) ⇔ cC(aq) + dD(aq)
To solve for Ksp it is necessary to take the molarities or concentrations of the products and multiply them. If there are coefficients in front of any of the products you rais the product to the coefficient as a power (as well as multiply the concentration by the coefficient)
Ksp = [cC]c [dD]d
What is the atomic number of nitrogen?
7
(there are 7 protons in its nucleus)
What determines the pH that a color change of an indicator will be observed at?
An indicator will change color over a specific pH range.
What is the equivalent of a faraday?
A faraday is equivalent to one mole of electric charge
When an molecule is reduced in a reaction does it have a high or a low electron affinity?
When an molecule is reduced it accepts an electron so it can be determined to have a high electron affinity
When does a substance boil?
A substance boils when enough heat has been supplied to overcome the intermolecular forces
What is the ideal gas law assumption about volume and does it always apply?
The ideal gas law makes the assumption that molecules have no volume. But when the pressure is increased to a very high value, the volume of the gas molecules is no longer negligible
What is the formula for the ideal gas law
PV = nRT
What is a characteristic of a good insulator but a poor conductor?
Electrons in a good insulator cannot easily move from one atom to another. In insulators, the valence electrons are tightly bound to their atoms and it takes a great amount of energy to free them from their atomic energy levels.
Formula for density
d = m/V
Density = Mass / Volume
What is the description of the orbital geometry of an sp3 hybridized atom?
An sp3 hybridized atom has four equivalent orbitals, making the geometry tetrahedral
Example of sp3 hybridized atoms:
- C in CH4
- N in :NH3 (because it has a lone pair)
What does the atomic number represent?
Atomic number represents the number of protons in an atom.
What is the effective nuclear charge?
The effective nuclear charge is the attraction between the nucleus and the electrons
As atomic number increases in a horizontal row of the periodic table what happens to the effective nuclear charge?
As the number of protons increases (indicated by an increasing atomic number) the effective nuclear charge also increases
What is ionization energy?
The amount of energy required to remove an electron from an element
A high effective nuclear charge means a (high/low) first ionization energy?
A high effective nuclear charge means a high first ionization energy
How do you find the molecular formula?
The molecular formula is determined by counting the number of atoms of different elements in the structure of a compound
What is the empirical formula?
The empircal formula of a compound is the simplest whole-number ratio of the moles of the elements in a compound
How is electron affinity measured?
Electron affinity is a measure of the tendency of an element to gain electrons
What is the periodic trend of electron affinity?
Electron affinity increasing moving from left to right along a period on the periodic table (increases towards halogens)
What group is Magnesium a part of on the periodic table?
Magnesium is an alkaline earth metal
In order for an oxidation-reduction reaction to occur spontaneously, the cell potential (Ecell°) for the net reaction must be_____
In order for an oxidation-reduction reaction to occur spontaneously, the cell potential (Ecell°) for the net reaction must be positive
How is the cell potential (Ecell°) found for a redox reaction?
The cell potential (Ecell°) can be found by subtracting the standard reduction potential Ered° for the substance being oxidized from that of the substance being reduced.
What does it mean if two atoms are isoelectric?
If two atoms are isoelectric it means that they have the same number of electrons
Will a lighter or a heavier molecule diffuse faster?
A ligher molecule will diffuse faster than a heavier molecule
What does Avogadro’s law state?
Avogadro’s law states that equal volumes of different gases at the same temperature and pressure contain the same number of molecules.
What determines the position of equilibrium in a reaction?
The position of equilibrium in a reaction is determined soley by the difference in free energy between products and reactants.
How does a catalyst affect the rate of the reaction?
A catalyst speeds up the reaction by lowering the reactions activation energy. The catalyst does nothing to effect the energies of the products and reactants and therefore cannot affect the equilibrium.
What happens when an ionic substance dissolves?
Whan an ionic substance dissolves it dissociates into its constituent ions
A substance that is likely to be more soluble in a strong acid is one that___
A substance that is likely to be more soluble in a strong acid is one that has a basic anion to react with the H+ ions in solution.