A3 - 2 Flashcards
refrigeration, heat transfer, renewable, processing
quantity of energy required to raise the temperature of a unit mass by 1K
specific heat
can be thought of as a measure of disorder in a system.
if a gas or vapor is compressed without friction and without adding or removing heat during the process, the entropy of the process remains constant
entropy, S
temp at the critical point beyond of which there are no distinct phases
critical temp
point at which a substance can exist as solid, liquid, and gas in thermodynamic equilibrium
triple point
defined by saturation points where substances exists as saturated liquid, saturated vapor or mixtures of both
saturation line
the sum of all the energies of all molecules in a system
Internal Energy, U
the amount of energy possessed by a thermodynamic system that can be transferred between the system and its environment
Enthalpy, (H = U + PV)
THERMODYNAMIC PROCESSES
no change in pressure of the fluid
Isobaric
THERMODYNAMIC PROCESSES
no change in volume of the fluid
Isochoric/ Isometric
THERMODYNAMIC PROCESSES
no change in temperature of the system
Isothermal
THERMODYNAMIC PROCESSES
no heat transfer from or to the fluid
Adiabatic
THERMODYNAMIC PROCESSES
no change of entropy of the fluid
Isentropic
LAWS OF THERMODYNAMICS
when two bodies have equality of temperature with a third body, they in turn have equality of temperature with each other.
Zeroth law
THERMODYNAMIC PROCESSES
no change of enthalpy
Isenthalpic
a process which there is no change in enthalpy from state one to state two, h1 =h2; no work done, W=0; and the process is adiabatic, Q = 0
Throttling Process
also known as the Conservation of Energy principle, states that energy can neither be created nor destroyed, it can only change forms
first law of thermodynamics
Work done by system is usually ____ sign
positive sign (+)
Work done on the system is usually ____ sign
negative sign (-)
Law of Thermodynamics states that the state of entropy of the entire universe, as an isolated system, will always increase over time. The law also states that the changes in the entropy in the universe can never be negative.
Second Law of Thermodynamics
a reversible cycle (a cycle having a succession of reversible processes such that the system periodically returns to its initial state)
carnot cycle
2 types of carnot cycle
Carnot heat engine
Carnot refrigeration cycle
Receives heat from low temperature to higher temperature via work (of compressor)
refrigeration cycle
a device that transfers heat energy from a source of heat to what is called a “heat sink”. Moves thermal energy in the opposite direction of spontaneous heat transfer, by absorbing heat from a cold space and releasing it to a warmer one
heat pump
If the objective of the device is to perform work it is a
heat engine
a thermodynamic quantity representing the unavailability of a system’s thermal energy for conversion into mechanical work, often interpreted as the degree of disorder or randomness in the system
entropy
if its objective is to supply energy to a body it is a
heat pump
if its objective is to extract energy from a body it is a
refrigerator
A pure substance is _______. It may exist in more than one phase, but each phase must have the same chemical composition.
homogeneous
After all the solid is melted, the temperature of the liquid again rises until vapor just begins to form. This state is called the _______.
saturated liquid state
Gases tend to approach the properties of ideal gas on the following conditions:
As the molecular weight ______
As the pressure _______
As the temperature ______
As the molecular weight decreases
As the pressure decreases
As the temperature increases
Momentum transfer is energy (in form of momentum) in transit due to velocity difference
Newton’s law on Viscosity
the total pressure of the mixture is equal to the sum of the individual pressures, if each gas separately occupied the space
dalton’s law of partial pressures
Heat transfer is energy in transit due to a temperature difference.
Fourier’s law
MECHANISMS OF HEAT TRANSFER
Transfer of thermal energy due to molecular vibrations
conduction
Mass transfer is mass in transit due to concentration difference
Fick’s law on mass diffusion
MECHANISMS OF HEAT TRANSFER
Transfer of thermal energy due to electron configuration
radiation
MECHANISMS OF HEAT TRANSFER
Transfer of thermal energy due to molecular motions
convection
the transfer of energy from the more energetic particles of a substance to the adjacent less energetic ones as a result of interactions between the particles
conduction
In the absence of any bulk fluid motion, heat transfer between a solid surface and the adjacent fluid is by ________
pure conduction
material property that appears in heat conduction analysis (normally in unsteady states) is the _______, which represents how fast heat diffuses through a material
thermal diffusivity
mode of energy transfer between a solid surface and the adjacent liquid or gas that is in motion, and it involves the combined effects of conduction and fluid motion.
convection
In gases and liquids, conduction is due to the collisions and diffusion of the molecules during their random motion
conduction
The faster the fluid motion, the _____ convection heat transfer
greater
Convection is called _____ if the fluid is forced to flow over the surface by external means such as a fan, pump, or the wind.
forced convection
the transfer of energy by _____ does not require the presence of an intervening medium. In fact, energy transfer by radiation is fastest (at the speed of light) and it suffers no attenuation in a vacuum.
radiation
The rate of convection heat transfer is observed to be proportional to the temperature difference, and is conveniently expressed by
Newton’s law of cooling
The maximum rate of radiation that can be emitted from a surface at an absolute temperature Ts (in K or R) is given by the
Stefan-Boltzmann Law
The idealized surface that emits radiation at thismaximum rate is called a ____, and the radiation emitted by a blackbody is called _____
blackbody
blackbody radiation
Convection is called _____ if the fluid motion is caused by
buoyancy forces that are induced by density differences due to the variation of temperature
in the fluid.
natural (or free)
convection
With values in the range 0 to 1, this property provides a measure of how efficiently a surface emits energy relative to a blackbody.
emissivity
Another important radiation property of a surface is its _____, α which is the fraction of the radiation energy incident on a surface that is absorbed by the surface.
Like emissivity, its value is in the range 0 to 1.
absorptivity
Heat transfer problems are often classified as being ____ (also called steady state) or _____ (also called unsteady).
steady
transient
-The term steady implies no change with time at any point within the medium, while transient implies variation with time or time dependence.
ratio of the heat transfer resistances inside of a body and at the surface of a body
biot number
ratio of convective to conductive heat transfer at a boundary in a fluid
nusselt number
ratio of the buoyancy to viscous force acting on a fluid. used in natural convection problems
grashof number
analogous to grashof number. used in force convection problems
reynold’s number
ratio of sensible to latent heat
stefan number
ratio of momentum diffusivity to thermal conductivity
prandtl number
ratio of conductive transport rate to the rate of thermal energy storage
fourier number
the high value of volume flow per ton with ____ makes it suitable for service in centrifugal compressors. _____ and R113 are the most-used refrigerants in centrifugal compressor system.
refrigerant 11
this is the most widely used refrigerant. It is used primarily with reciprocating compressors for service in household refrigeration appliances, commercial and industrial air conditioning, and in a multitude of other types of refrigeration systems. _____ possesses desirable properties, having convenient operating pressures, low power requirement per ton, and is nontoxic and noncorrosive.
refrigerant 12
like R12, is nontoxic and has a low power requirement per ton. _____ is competitive with Refrigerant 12 in small air-conditioning units. It is competitive with ammonia in industrial low-temperature systems in cases where toxicity of the refrigerant is of concern.
refrigerant 22
the vapor in the air is saturated
saturated air
air containing superheated vapor
unsaturated air
heat does not affect the temperature of the substance but damage its state
Latent heat
is the heat absorbed or given by a substance that changes its temperature
Sensible heat
sum of latent heat and sensible heat
Total heat
is the ratio of sensible heat load to the total heat load
SENSIBLE HEAT RATIO (sensible heat factor)
ratio of partial pressure of water vapor in the air to the saturation pressure corresponding to the temp of the air
relative humidity
the difference between the reading of the dry bulb and wet bulb temperature
wet bulb depression
the saturation temperature corresponding to the actual partial pressure of the stem in air or the temperature at which condensation of the moisture begin when the air is cooled at constant pressure
dew point temperature
the ratio of the air humidity ratio (SH or W) to the humidity ratio of saturated air ( SHs or Ws ) at the same temperature
degree of saturation
mixture of dry air and water vapor is the sum of the enthalpy of the dry air and the enthalpy of the water vapor.
enthalpy
located on vertical lines angling up and to the left from the dry-bulb temperature scale
specific volume
a material quality which describes how readilty a substance vaporizes
volatility
The lowest temperature at which a liquid can give off vapor to form an ignitable mixture in air near the surface of the liquid.
flash point
are liquids that has flashpoint below 37.8°C (100°F)
flammable liquids
are substances that has flashpoints above 37.8°C (100°F) and below 93.3°C (200°F)
combustible liquids
All of the hydrogen in the fuel is converted into water and all of the carbon is converted into carbon dioxide
stoichiometric combustion
The lowest temperature at which a liquid can flow.
pour point
The lowest temperature at which the vapour will continue to burn for at least 5 seconds.
fire point
Chemical reaction of carbon and hydrogen in the fuel with oxygen in the air to form water and other exhaust products
combustion