A2 2 Definitions Flashcards

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1
Q

Transition metals

A

An element which forms at least one stable ion with a partially filled d subshell

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2
Q

Ligand

A

An ion or molecule with a lone pair of electrons which forms a co-ordinate bond with a central atom or ion complex

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3
Q

Metal complex

A

A central metal atom or ion with ligands bonded by co-ordinate bonds

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4
Q

Co-ordination number

A

The number of co-ordinate bonds to a central metal atom or ion complex

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5
Q

Monodentate ligand

A

A ligand which uses only one lone pair of electrons to form a co-ordinate bond with a central metal atom or ion in a complex

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6
Q

Bidentate ligand

A

A ligand which uses two lone pairs of electrons to form two co-ordinate bonds with a central metal atom or ion in a complex

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7
Q

Polydentate ligand

A

A ligand which uses many lone pair of electrons to form more than two co-ordinate bonds with a central metal atom or ion in a complex

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8
Q

Base peak

A

Peak of greatest abundance in a mass spectrum

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9
Q

Molecular ion peak

A

A peak produced by an ion formed by the removal of one electron from a molecule

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10
Q

M+1 peak

A

A peak produced by a molecular ion with an increased mass due to the presence of one carbon-13 atom

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11
Q

Fragmentation ion

A

A positively charged ion produced when the molecular ion breaks apart

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12
Q

Low resolution nmr

A

A spectrum which does not show the spin spin splitting pattern

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13
Q

High resolution nmr

A

A spectrum which does show the spin spin splitting pattern

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14
Q

Doublet

A

A signal which appears as a pair of lines of equal intensity

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15
Q

Triplet

A

A signal which appears as three lines in the approximate intensity ratio (1:2:1)

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16
Q

Quartet

A

A signal which appears as four lines in the approximate intensity ratio (1:3:3:1)

17
Q

Back titration

A

Method where an excess of a reagent is reacted with a sample. The unreacted reagent is then determined by titration

18
Q

Rf values

A

Retardation factor, this is calculation using the expression: Rf=distance moved by spot/distance moved by solvent

19
Q

Retention time

A

The time taken from injection until a component reaches the detector

20
Q

Standard electrode potential

A

The potential difference measured when a half cell is connected to the standard hydrogen electrode under standard conditions

21
Q

E.m.f

A

The potential difference measured when two half cells are connected