A-LEVEL Chemistry: 3.1.1: Atomic Structure PMT & CR Flashcards
What is ‘Mass Number’?
The Number of Protons & Neutrons in a specific Atom. It is Specific to the Isotope.
What is ‘Atomic Number’?
Atomic Number is the Number of Protons in the Nucleus of the Atom.
What is ‘Relative Atomic Mass’?
The Mass of an Atom of an Element, Relative to 1/12th of a C12 Atom.
What is ‘Relative Formula Mass’?
The Sum of the Atomic Masses of all Atoms in the Formula of a Substance, Relative to 1/12th the Relative Atomic Mass of a C12 Atom.
What is ‘Relative Molecular Mass’?
The Average Mass of a Molecule, Relative to 1/12th the Relative Atomic Mass of a C12 Atom. The Sum of all Atoms within the Molecule.
What is the Difference between Relative Formula Mass & Relative Molecular Mass?
Relative Formula Mass is usually Used for Compounds which are not Molecules, eg Ionic Compounds. On the other hand, Relative Molecular Mass is usually Used for Compounds which are Molecules, eg Covalent Compounds.
Why do Many of the Atomic Measurements begin with ‘Relative’? (eg RAM, RFM, RMM…)
Because all the Measurements are Relative to 1/12th the Mass of a C12 Atom.
What is a ‘Mole’?
A Mole is a Set Number of Molecules. It is a Unit of Measurement Used in Chemistry. 1 Mole = 6x10^23 (Avogadro’s Constant).
One Mole of Anything Contains…
6.022x10^23 of those things. (Avogadro’s Constant).
What is ‘Avogadro’s Constant’?
6.022x10^23. The Number of Substance in 1 Mole.
1 Mole = 6.022x10^23
What is the Relative Mass of a Proton?
1.
What is the Relative Charge of a Proton?
+1.
What is the Relative Mass of a Neutron?
1.
What is the Relative Charge of a Neutron?
0.
What is the Relative Mass of an Electron?
1/1840.
What is the Relative Charge of an Electron?
-1.
What are ‘Isotopes’?
Isotopes are Atoms with the Same Number of Protons, but Different Numbers of Neutrons.
Isotopes have similar ___ Properties. Why?
Chemical. Because they have the Same Electronic Structure.
Isotopes may have Slightly Varying ___ Properties. Why?
Physical. Because the have Different Masses.
The ___ for Atomic Structure has Evolved over Time. Why is this?
Model. Because Knowledge & Scientific Understanding Changes.
What is the ‘Plum Pudding Model’?
An Old Model of Atoms that Consisted of a Sphere ‘Cloud’ of Positive Charge, with Small Balls of Negative Charge Distributed Evenly within it.
Explain the Current Understanding of the Structure of an Atom.
The Atom Consists of a Small, Dense Central Nucleus, Surrounded by Orbiting Electrons Organised in Electron Shells.
Who Discovered the Current Understanding of the Atom? When?
Rutherford, in his Scattering Experiment in 1911.
What does the ‘Nucleus’ Consist of?
Protons & Neutrons.
What is the Overall Charge of the Nucleus? Why is this?
The Nucleus has an Overall Positive Charge. This is Because it Consists of Protons (+1) & Neutrons (0).
The Nucleus Contains Almost the Entire ___ of the Atom.
Mass.
In a Neutral Atom, the Number of ___ is Equal to the Number of ___. Why is this?
Protons, Electrons. This is Due to the Relative Charges. (+1 & -1).
What is the ‘Relative Charge’ of the 3 Sub-Atomic Particles in an Atom? (3)
-Proton: +1
-Neutron: 0
-Electron: -1
What is the ‘Relative Mass’ of the 3 Sub-Atomic Particles in an Atom? (3)
-Proton: 1
-Neutron: 1
-Electron: 1/1840
What is the Relative Mass of an Electron?
1/1840
How can you Calculate the Maximum Number of Orbiting Electrons that can be Held by a Single Shell?
2n^2
Where n is the Number of the Shell.
What is the Maximum Number of Electrons that Can be Held by Shell 2?
Max. Electrons in Shell 2 = 2(2^2) = 8 Electrons
What Must Happen Before the Next Shell can Hold any Electrons?
Each Electron Shell Must Fill Before the Next one Can Hold any Electrons.
Each Electron Shell Must ___ Before the Next one Can Hols any Electrons.
Fill.
What Symbol is ‘Mass Number’ Represented by?
A
Mass Number = …
No. of Protons + No. of Neutrons
Atomic Number = …
Number of Protons in the Atom
What Symbol is ‘Atomic Number’ Represented by?
Z
What Symbol is ‘Relative Atomic Mass’ Represented by?
Ar
What is ‘Relative Atomic Mass’?
The Mean Mass of an Atom of an Element, Relative to 1/12th the Mean Mass of an Atom of the Carbon-12 (C12) Isotope.
What are ‘Isotopes’?
Isotopes are Atoms of the Same Element with the Same Atomic Number, but with a Different Number of Neutrons, Resulting in a Different Mass Number.
Neutral Atoms of Isotopes Will have the Same ___ Properties. Why is this?
Chemical. Because their Proton Number & Electron Configuration is still the Same. The Sharing & Transferring of Electron is Unaffected.
Neutral Atoms of Isotopes Will have Different ___ Properties. Why is this?
Physical. Because they have a Different Mass Number (Due to a Different Number of Neutrons).
What are ‘Ions’?
Ions are Atoms with an Overall Charge (+ or -).
How are ‘Ions’ Formed?
Ions are Formed when an Atom Gains or Loses Electrons, Meaning that it is No Longer Neutral, & Will now Have an Overall Charge.
Explain What happens when an Atom Gain / Loses Electrons. (2)
-When an Atom Gains an Electron, Electrons > Protons in the Atom, so the Atom Becomes a - Ion, with an Overall Negative Charge.
-When an Atom Loses an Electron, Electrons < Protons in the Atom, so the Atom Becomes a + Ion, with an Overall Positive Charge.
What is ‘Mass Spectrometry’?
This is an Analytical Technique Used to Identify Different Isotopes & Find the Overall Relative Atomic Mass of an Element.
What is ‘Time of Flight (TOF) Mass Spectrometry’?
This Form of Mass Spectrometry Records the Time it Takes for Ions of Each Isotope to Reach a Detector. Using this, Spectra can be Produced, Showing each Isotope Present.
Explain the Process of ‘Time of Flight (TOF) Mass Spectrometry’: (5)
-1) Ionisation: A Sample of an Element is Placed into the Sample Chamber. The Sample is then Vapourised & Injected into the Mass Spectrometer, Where a High Voltage is Passed Over the Chamber. This Causes Electrons to be Removed from the Atoms (they are Ionised), Leaving +1 Charged Ions in the Chamber.
-2) Acceleration: These Positively Charged Ions are then Attracted Towards a Negatively Charged Detection Plate. This Negative Charge Causes the Ions to Accelerate. This Increases the Kinetic Energy of the Ions. All of the Ions with the Same Charge Will also have the Same Kinetic Energy.
-3) Ion Drift: Once the Ions Pass through the Negative Plate, they Stop Accelerating, & they Drift Down the Chamber, Towards the Detector. The Ions Drift Down the Chamber at Different Velocities, with the Lighter Ions Moving Faster than the Heavier Ions.
-4) Detection: When the Positive Ions Hit the Negatively Charged Detection Plate, they Gain an Electron, Producing a Flow of Charge (a Current). The Greater the Current Produced, the Greater the Abundance of that Isotope.
-5) Analysis: These Current Values are then Used in Combination with the Flight Times to Produce a Spectra Print-Out with the Relative Abundance of Each Isotope Displayed.