_____ Flashcards
This is the smallest energy that can be emitted (or absorbed) in the form of electromagnetic waves
QUANTUM
A phenomena where electrons from the surface of certain metals exposed to light of at least a certain minimum frequency
PHOTOELECTRIC EFFECT.
An electron bound to the nucleus behaves like a
STANDING WAVE.
First known laser
RUBY LASER
It states that it is impossible to form an image of an object that is smaller than half the wavelength of the light used for observation
LAW OF OPTICS
A quantum number that relates the average distance of the electrons from the nucleus in a particular orbital.The larger this, the greater the average distance of an electron in the orbital from the nucleus and therefore the larger the orbital.
(PRINCIPAL QUANTUM NUMBER (N))
Group of elements which have incompletely filled d subshells
TRANSITION METALS
Series of elements that are not usually found in nature but is always synthesized
Actinide series
Group of elements that have incompletely filled 4f subshells
LANTHANIDES OR RARE EARTH
This is defined as a reduction in the effectivenuclear chargeon theelectroncloud, due to a difference in the attraction forces of theelectronson the nucleus.
SHIELDING EFFECT
Atoms of elements with low ionization energies tend to form
CATIONS
Atoms with high electron affinities tend to form
ANIONS
The elements that are most likely to form cations in ionic compounds are
ALKALI METALS AND ALKALI EARTH METALS
These are elements that are likely to form anions
HALOGENS AND OXYGEN
A poisonous white powder used in lowering the melting point of solders in manufacturing ceramics.
LITHIUM FLUORIDE
This is the energy required to completely separate one mole of a solid ionic compound into gaseous ions-
LATTICE ENERGY
This cycle relates lattice energies of ionic compounds to ionization energies, electron affinities, and other atomic and molecular properties
BORN HABER CYCLE
To form an ionic bond the electronegativity difference between two bonding atoms should be-
2.0 or more.
Violators of Octet Rule:
• Atoms of the second period elements cannot have more than eight valence electrons around the central atom.
-• Atoms of elements in and beyond the third period of the periodic table form some compound in which more than eight electrons surround the central atom.
Mathematicalequationthat describes the changes over time of a physical system in which quantum effects, such as wave–particle duality, are significant.
Schrodinger Equation
Which rule is followed by Hydrogen
a. duet rule b. octet rule c. triad rule
a. duet rule
Who proposed the hexagonal structure of benzene?
August Kekule
Resonance structures with formal charges greater than____ are usually considered highly implausible and can be discarded.
+2 or -2
Which period of elements in the table cannot have an expanded octet?
Second-period
The most reactive metals are in ____ and the most reactive nonmentals in ___.
Group 1A, Group 7A
What element melts in a person’s body?
Gallium
Mendeleev proposed the existence of an unknown element he called ____ which has properties close to Gallium.
eka-aluminum
His work on periodic classification of elements is regarded by many as the most significant achievement I chemistry in nineteenth century.
Dmitri Mendeleev
He discovered the chemical affinity of hemoglobin for oxygen.
Julius Lothar Meyer
The non-valence electrons are called
core electrons
The representative elements are the elements in _____, all of which have incompletely filled s or p subshells of the highest principal quantum number.
Groups 1A through 7A
The transition metals are the elements in ____, which have incompletely filled d subshells.
Group 1B, 3B through 8B
The ____ is the nuclear charge felt by an electron when both the actual nuclear charge and the repulsive effects of other electrons are taken into account.
effective nuclear charge
The increase in effective nuclear charge from_____ a period and from ____ in a group for representative elements.
left to right across a period and from top to bottom
It is one half the distance between the two nuclei in two adjacent metal atoms or in a diatomic molecule.
Atomic radius
The radius of a cation or an anion.
Ionic radius
TRUE OR FALSE. The radii of tripositive ions are smaller than those of dipositive ions.
. TRUE
How many Elements are gases under atmospheric conditions?
11 Elements .
They are the Group 8A elements and the other five are H2, N2, O2, F2, and Cl2.
How many Elements are liquid under atmospheric conditions?
There are only two liquid elements at 25C. These are mercury and bromine. Francium melts at 23C.
It is the minimum energy required to remove an electron from a gaseous atom in its ground state.
Ionization energy
Electron affinity is positive if the reaction is_____.
Negative if the reaction is ____.
EXOTHERMIC; ENDOTHERMIC
Similarities between pairs of elements in different groups and periods of periodic table.
Diagonal Relationship
The charge ion divided by its volume.
Charge density
Peroxides (contains O22- ion). ______ (contains O2- ion).
Superoxides
This oxide display both the acidic and basic properties.
Amphoteric
This should not be stored in Pyrex Glass.
NaOH
Ramsay and Lord Rayleigh discovered _____ which means “the lazy one”. Also in 1898 Ramsay isolated helium from uranium ores.
Argon
Ramsay and his student, Morris Travers set out to find the unknown gases. They used a ____ to first produce liquid air. Applying a technique called ______, they then allowed the liquid air to warm up gradually and collected components that boiled off at different temperatures. In this manner, they analyzed and identified three new elements—neon, krypton, and xenon—in only three months. Three new elements in three months is a record that may never be broken!
refrigeration machine; fractional distillation
Chemists define_____ as directed energy change resulting from a process.
work
is the energy associated with the random motion of atoms and molecules. The more vigorous the motion of the atoms and molecules in a sample of matter, the hotter the sample is and the greater its thermal energy.
Thermal energy
is stored within the structural units of chemical substances; its quantity is determined by the type and arrangement of constituent atoms.
Chemical energy
study of heat change in chemical reactions.
Thermochemistry
In thermodynamics, we study changes in the _____ which is defined by the values of all relevant macroscopic properties, for example, composition, energy, temperature, pressure, and volume.
state of a system
Melting 1 mole of ice at 0°C
endothermic process
Burning 1 mole of methane in oxygen gas
exothermic process
Sodium reacting with water to can also form
hydrogen gas
Carbon monoxide burns in air to form
carbon dioxide
is the measurement of heat changes
Calorimetry
The “sea level” reference point for all enthalpy expressions is called
standard of enthalpy of formation
By convention, the standard enthalpy of formation of any element in its most stable form is
zero
White phosphorus burns in air to form
P4O10.
can be stated as follows: When reactants are converted to products, the change in enthalpy is the same whether the reaction takes place in one step or in a series of steps.
Hess’s law
is called the father of thermochemistry.
Germain Henri Hess
An ______ has a high flame temperature (3000°C) and is used to weld metals.
oxyacetylene torch
The energy required to completely separate one mole of a solid ionic compound into
gaseous ions is called
lattice energy (U).
Which of the following is a ketose?
a. fructose b. glucose c. sucrose d. lactose
a. fructose