111111 Flashcards

1
Q

the conversion of molecular nitrogen into
nitrogen compounds, atmospheric nitrogen gas is converted into nitrates and other
compounds suitable for assimilation by algae and plants

A

nitrogen fixation

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2
Q

the concentration of ozone

and other gases is low, and the temperature decreases with increasing altitude

A

mesosphere

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3
Q

The formation of ozone in this region begins with
the _______ of oxygen molecules by solar radiation at wavelengths below
240 nm

A

photodissociation

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4
Q

In the stratosphere, a stream of air known as the _____ circles Antarctica in winter.

A

“polar

vortex”

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5
Q

If the atmosphere did not contain carbon dioxide, Earth would be ___ cooler

A

30C

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6
Q

Venus contains____ Co2 and has a temperature of 730K.

A

97%

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7
Q

The solar radiant energy received by Earth is distributed over a band of wavelengths
between _____, but much of it is concentrated in the 400- to
700-nm range, which is the visible region of the spectrum.

A

100 and 5000 nm

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8
Q

_____molecule can vibrate in more than one way. Water, for example,
can vibrate in three different ways.

A

polyatomic

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9
Q

Because atmospheric CO2 in equilibrium with rainwater would not be
expected to result in a pH less than____.

A

5.5

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10
Q

is also added to lakes and soils in a process called liming to reduce their acidity caused by SO2

A

Quicklime

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11
Q
Spreading
calcium oxide (CaO) over acidifi edsoil. This process is called
A

liming

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12
Q

: is a powerful lachrymator, or tear producer, and causes breathing difficulties

A

PAN peroxyacetyl nitrate

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13
Q

formed by the reactions of automobile exhaust in the presence of sunlight.

A

photochemical smog

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14
Q

It is the secondary

pollutants—_______—that are responsible for the buildup of smog.

A

NO2 and O3

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15
Q

Automobile exhaust consists mainly of NO, CO, and various unburned hydrocarbons.
These gases are called _________ because they set in motion a series
of photochemical reactions that produce secondary pollutants.

A

primary pollutants

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16
Q

The dispersion of these droplets in air, called _____, scatters
sunlight and reduces visibility. This interaction also makes the air look hazy.

A

aerosol

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17
Q

The

common indoor pollutants are

A

radon, carbon monoxide and carbon dioxide, and

formaldehyde.

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18
Q

After cigarette smoking, _____ is the leading
cause of lung cancer in the United
States.

A

radon

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19
Q

All isotopes of radon are radioactive, but

____ is the most hazardous because it has the longest half-life—3.8 days.

A

radon 222

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20
Q

The concentration of ____
in the blood of regular smokers is two to
five times higher than that in nonsmokers.

A

carboxyhemoglobin

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21
Q

often described as a measure of how
spread out or dispersed the energy of a system is among the different possible ways
that system can contain energy.

A

Entropy

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22
Q
shows that
the spacing between translational energy
levels is inversely proportional to the
volume of the container and the mass
of the molecules.
A

Quantum mechanical analysis

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23
Q

Engraved on _____ tombstone in Vienna is his famous
equation. The “log” stands for “loge,”
which is the natural logarithm or ln.

A

Ludwig Boltzmann’s

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24
Q

Processes that lead
to an increase in entropy of the
system:

A

(a) melting: Sliquid . Ssolid;
(b) vaporization: Svapor . Sliquid;
(c) dissolving: Ssoln . Ssolute 1
Ssolvent; (d) heating: ST2 . ST1.

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25
is the absolute | entropy of a substance at 1 atm and 25°C.
Standard entropy
26
The entropy of the universe increases in a spontaneous | process and remains unchanged in an equilibrium process.
second law of thermodynamics:
27
the entropy of a perfect crystalline | substance is zero at the absolute zero of temperature.
third law of thermodynamics
28
is a machine that converts thermal energy to work
heat | engine
29
The change in free energy (DG ) of a system for a constant-____ proces.
temperature
30
, is an extremely valuable inorganic substance used in steelmaking, production of calcium metal, the paper industry, water treatment, and pollution control
Calcium oxide (CaO), also called quicklime,
31
Le Châtelier’s principle predicts that the forward, _______ is favored by heating.
endothermic rxn
32
True or False. Sooner or later a reversible reaction will | reach equilibrium.
True
33
is the product of the charge Q and the distance r between the charges
dipole moment
34
Dipole moments are usually expressed in debye units (D), named for ______ made many signifi cant contributions in the study of molecular structure, polymer chemistry, X-ray analysis, and electrolyte solution.
Peter Debye.
35
This is a naturally occurring substance with a range of chemical composition
MINERAL
36
A mineral deposit concentrated enough to allow economical recovery of a desired metal-
ORE
37
Solid solution either of two or more metals or of a metal or metals with one or more nonmetals.
ALLOY
38
Example of ferromagnetic metal
COBALT
39
An alloy of mercury with another metal or metals-
AMALGAM
40
Lithium is found in what mineral?
Spodumene
41
Berrylium is from what mineral?
BERYL
42
Why is production of metal a reduction process?
Because metals in their combined form always have positive oxidation number.
43
This process leads to the production of SO2 and acid rain
EXTRACTION OF IRON FROM FES2
44
A procedure carried out at high temperature
PYROMETALLURGY
45
Mixture of calcium silicate and calcium aluminate that remains molten at the furnace temperature
SLAG
46
CaCO3 and other compounds that are used to form a molten mixture with the impurities in the ore for easy remova
FLUX
47
Other name for cast Iron
PIG IRON
48
What kind of process is the conversion of iron to steel?
OXIDATION PROCESS
49
If the main impurities in the steel making are silicon and phosphorus, what type of flux should be used?
BASIC FLUX- CaO
50
If the main impurities in the steel making is manganese, what type of flux should be used?
ACIDIC FLUX – SIO2
51
At high temperatures, iron and carbon in steel combine to form
IRON CARBIDE OR CALLED CEMENTITE
52
Heating the steel to some appropriate temperature for a short time and then cooling it rapidly in order to give it the desired mechanical properties-
TEMPERING
53
Metals that have low boiling points such as mercury, magnesium, and zinc, can be separated from other metals
FRACTIONAL DISTILLATION
54
The purification of nickel-
MOND PROCESS
55
Why does the metal’s ability to conduct electricity decreases with increasing temperature?
Because the enhanced vibration of atoms at higher temperatures tends to discrupt the flow of electrons.
56
The ability of a semiconductor to conduct electricity can also be enhanced by adding small amounts of certain impurities to the element by the process
DOPING
57
. Impurities that provide conduction electrons
DONOR IMPURITIES
58
Solids containing donor impurities are called
N-type semiconductors
59
Impurities that are electron deficient are called
ACCEPTOR IMPURITIES
60
Solids containing acceptor impurities are called
P-TYPE SEMICONDUCTORS
61
Lightest metal known
LITHIUM
62
Why do alkali metals never occur naturally in elemental form?
because of their great chemical reactivity
63
Sodium and potassium are about equally abundant in nature, they occur in minerals such as
ALBITE AND ORTHOCLASE
64
Mineral name for NaCl
HALITE
65
Mineral name for NaNO3
CHILE SALTPETER
66
Mineral name for KCl
SYLVITE
67
These are powerful reducing agents
METAL AMMONIA
68
Na2CO3 is produced by what process
SOLVAY
69
The sixth most plentiful element in the earths crust
MAGNESIUM
70
. Earthscrust contains about ___ percent of calcium
- 3.4
71
This is produced by the thermal decomposition of calcium carbonate
- QUICKLIME
72
Principal ore of aluminum-
BAUXITE
73
. Anhydrous aluminum oxide
CORUNDUM
74
Corundum is reduced to aluminum by
HALL PROCESS
75
. A discrete molecular species possessing bridging H atoms like diborane
Aluminum hydride
76
Waste material of an ore-
GANGUE