9. Bronsted Lowry acids and bases Flashcards
Bronsted-Lowry acid is a
e.g. HCl, H2SO4
proton H+ donor
e.g. HCl(g) -> H+(aq) + Cl-(aq)
H2SO4(aq) -> H+(aq) + HSO4-(aq)
Bronsted Lowey base is a
e.g.NH3
proton H+ acceptor
NH3(aq)+ H+(aq) -> NH4+(aq)
monobasic acids
e.g. HCl
each molecule can release 1 proton
HCl(aq) -> H+ (aq) + SO4-(aq)
dibasic acids
e.g. H2SO4
each molecule can release 2 protons
H2SO4(aq) -> H+(aq) + HSO4- (aq)
HSO4-(aq) -> H+(aq) + SO42-(aq)
tribasic acids
e.g. H3PO4
each molecule can release 3 protons
H3PO4(aq) -> H+(aq) + H2PO4-(aq)
H2PO4-(aq) -> H+(aq) + HPO42-(aq)
HPO42-(aq) -> H+(aq) + PO43-(aq)
Conjugate acid base pair
e.g. acid HNO2
and base NO2-
two species that transform into each other by gain or loss of a proton
HNO2 H+ + NO2- (change in to one another by loosing or gaining H+
acid and base equilibria involve 2 acid-base pairs (conjugate)
e.g. HNO2(aq) + H2O(l) -> H3O+(aq) + NO2-(aq)
forward direction
acid HNO2 releases H+ to form its conjugate base NO2-
base H20 accepts proton to form its conjugate acid H3O+
reverse direction
acid H3O+ releases its proton to form conjugate base H2O
base NO2- accepts proton to form conjugate acid HNO2
strong acids..
where as weak acids…
fully dissociate. one way direction
only partially dissociate. reversible reaction
strength of acid determined by conc of H+/H3O+
strong bases..
whereas weak bases..
fully dissociate high one way reaction OH- conc
partially dissociate reversible reaction low OH- conc