7. Equilibrium and Kp Flashcards
the mole fraction of a substance is
a measure of how much of a given substance is present in a reaction mixture
the partial pressure of a substance is
the pressure an individual gaseous substance would exert if it occupied a whole reaction vessel on its own
how to calculate mol fraction e.g. of substance A
mole fraction, X subscriptA= number of moles of substance A / total number of moles of all substances
how to calculate partial pressure e.g of substance A
P superscriptA = mole fraction x total pessure
units of pressure used within chemistry
atmospheres, atm
pascals, Pa (SI unit for pressure USE THIS)
newtons per square metre (Nm-2)
1atm=1.01 x 10 to the power of 5 Pa OR 101 kPa
1Pa =1Nm-2
brackets used in Kp expressions
round brackets denote partial pressures
Kp is used for
reactions involving gases
calculating equilibrium constant Kp
aA+bB cC + dD
Kp= PRODUCTS /
REACTANTS
Kp= (PC)c (PD)d /
(PA)a (PB)b
the expression for Kp when a reaction is hetrogeneous will change
solids not included in expression
pure liquids not included in expression
if Kp is greater than 1
more products than reactants at equilibrium
if Kp is less than 1
more reactants than products at equilibrium
Kp is constant as long as there is a
constant temperature