7. Equilibrium and Kp Flashcards

1
Q

the mole fraction of a substance is

A

a measure of how much of a given substance is present in a reaction mixture

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2
Q

the partial pressure of a substance is

A

the pressure an individual gaseous substance would exert if it occupied a whole reaction vessel on its own

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3
Q

how to calculate mol fraction e.g. of substance A

A

mole fraction, X subscriptA= number of moles of substance A / total number of moles of all substances

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4
Q

how to calculate partial pressure e.g of substance A

A

P superscriptA = mole fraction x total pessure

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5
Q

units of pressure used within chemistry

A

atmospheres, atm
pascals, Pa (SI unit for pressure USE THIS)
newtons per square metre (Nm-2)

1atm=1.01 x 10 to the power of 5 Pa OR 101 kPa

1Pa =1Nm-2

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6
Q

brackets used in Kp expressions

A

round brackets denote partial pressures

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7
Q

Kp is used for

A

reactions involving gases

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8
Q

calculating equilibrium constant Kp

A

aA+bB cC + dD

Kp= PRODUCTS /
REACTANTS

Kp= (PC)c (PD)d /
(PA)a (PB)b

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9
Q

the expression for Kp when a reaction is hetrogeneous will change

A

solids not included in expression

pure liquids not included in expression

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10
Q

if Kp is greater than 1

A

more products than reactants at equilibrium

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11
Q

if Kp is less than 1

A

more reactants than products at equilibrium

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12
Q

Kp is constant as long as there is a

A

constant temperature

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