8.1 thermodynamics Flashcards
thermodynamics
energy transformations that occur in a collection of matter
system vs surroundings
what is being studied
vs
everything else
isolated system
unable to exchange matter or energy with surroundings
open system
energy and matter can be transferred between system and surroundings
first law of thermodynamics
AKA the principle of conservation of energy
the energy of the universe is constant
- no creation or destroying energy
- only transforming and transferring energy
second law of thermodynamics
every energy transfer or transformation increases the entropy of the universe
(basically, every chemical reaction loses some energy to heat-unusable energy)
and
for a process to occur spontaneously, it has to increase the entropy of the universe
(spontaneous reactions release heat)
heat
random motion of atoms
- cannot do work
- “useless” energy
loss fusible energy makes the universe
more disordered
increase entropy
entropy
a measure of disorder or randomness
how does entropy increase in the universe
- -increase of heat
- and less ordered forms of matter (small molecules like CO2 exhaled)
spontaneous reaction
occurs on its own
-increases the entropy of the universe
non spontaneous
cannot occur on its own
-needs energy added to system to work
why do complex organisms evolve from simple organisms if entropy has to increase
entropy of both system and surrounding s increase