7.5 Quantitative Changes In Equilibrium Flashcards
Does changing concentration change the equilibrium constant?
No
Explain the carbonic acid buffer system to increase blood pH
- CO2 (aq) + H2O (l) <-> H2CO3 (aq) <-> HCO3 + H+
- Administering carbonate ions causes equilibrium to shift left reducing carbonic acid concentration to raise blood pH
What is the Reaction Quotient (Q)
The products of concentrations of products divided by product of concentrations of reactants for a reaction not necessarily at equilibrium
What are instantaneous concentrations
Concentrations that occur together at a particular time in the progress of a chemical reaction
What happens if Q<K
System has too much reactant, rxn shifts right
What happens if Q=K
System is at equilibrium
What happens if Q>K
System has too much product, rxn shifts left
What is the 100 rule
If the initial reactant divided by the value of K is greater than 100, then a change in concentration can be ignored to simplify an equation mathematically
What is the 5% rule
If (Initial concentration - Final concentration) / Initial concentration x 100 is between 0 and 5%, using the 100 rule was appropriate