7. Alkyl halides Flashcards
Classes of Alkyl Halides
Methyl halides
Primary
Secondary
Tertiary
Geminal dihalide.
Two halogen atoms
are bonded to different carbon. T or F?
False. Two halogen atoms are bonded to the SAME carbon
Vicinal dihalide.
Two halogen atoms
are bonded to the same carbons
False. Two halogen atoms
are bonded to adjacent carbons.
Uses of Alkyl Halides
Solvents - dry cleaning fluid • Reagents for synthesis of other compounds • Anesthetic: Halothane • Freons: CFC’s • Pesticides
Boiling Point
Greater intermolecular forces, higher bp
Greater mass, higher b.p.
Spherical shape decreases b.p.
Density
Alkyl fluorides and chlorides less dense
than water. T or F?
True
Alkyl dichlorides, bromides, and iodides
less dense than water.
False. Alkyl dichlorides, bromides, and iodides
MORE dense than water.
Polarity and Reactivity
Halogens are more electronegative than C. T or F?
True.
carbon has partial
positive charge T or F?
True
Carbon cannot be attacked by a nucleophile
False. Carbon CAN BE attacked by a nucleophile
Halogen can leave with the electron pair.
True