6A: Buffer And Titrations Flashcards
What does the term: buffer effectiveness mean and what are the two factors
There is a limit to how much acid or base can be added to the buffer before its pH changes significantly
1. The relative amounts of acid and base
2. The absolute concentrations of acid and base
Buffering range
The pH range at which the buffer can be most effective
The buffering capacity
The amount of acid or base a buffer can comfortably neutralize
What ratio is a buffer most effective
0.1<[base]:[acid]<10
PH=pkA-1
PH=pKa+1
- What is the buffering Capacity equation
- Buffer capacity and concentration of buffer relationship
- What is the best capacity
- B=dnbase/dpH
- Capacity increases with increasing absolute concentration of buffer components
- Base:acid=1
What is the buffering capacity involving acids and bases
When does the expression reach a maximum
B=ln(10)x(nA—nHA)/(nA-+nHA)
NA-=nHA
What is occurring in a titration
A solution of a known concentration is gradually added to another solution of unknown concentration until the chemical reaction between the two solutions is complete
Equivalence point
The point at which the reaction is complete
Indicator
Substance changing color at the equivalence point
How many equivalence points will there be for a TRIprotic acid
3 different equivalence points
Why is it important to select the right indicator
The indicator must change its color at or near the equivalence point for the titration curve