6A: Buffer And Titrations Flashcards

1
Q

What does the term: buffer effectiveness mean and what are the two factors

A

There is a limit to how much acid or base can be added to the buffer before its pH changes significantly
1. The relative amounts of acid and base
2. The absolute concentrations of acid and base

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2
Q

Buffering range

A

The pH range at which the buffer can be most effective

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3
Q

The buffering capacity

A

The amount of acid or base a buffer can comfortably neutralize

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4
Q

What ratio is a buffer most effective

A

0.1<[base]:[acid]<10
PH=pkA-1
PH=pKa+1

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5
Q
  1. What is the buffering Capacity equation
  2. Buffer capacity and concentration of buffer relationship
  3. What is the best capacity
A
  1. B=dnbase/dpH
  2. Capacity increases with increasing absolute concentration of buffer components
  3. Base:acid=1
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6
Q

What is the buffering capacity involving acids and bases
When does the expression reach a maximum

A

B=ln(10)x(nA—nHA)/(nA-+nHA)
NA-=nHA

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7
Q

What is occurring in a titration

A

A solution of a known concentration is gradually added to another solution of unknown concentration until the chemical reaction between the two solutions is complete

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8
Q

Equivalence point

A

The point at which the reaction is complete

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9
Q

Indicator

A

Substance changing color at the equivalence point

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10
Q

How many equivalence points will there be for a TRIprotic acid

A

3 different equivalence points

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11
Q

Why is it important to select the right indicator

A

The indicator must change its color at or near the equivalence point for the titration curve

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