6. Crude OIl and hydrocarbons Flashcards
How is crude oil formed?
Millions of years ago marine (sea) creatures died and fell to the bottom of the oceans.
Layers of other creatures and sediment built up on top.
The layers of died marine creatures were heated and compressed and eventually turned into oil and gas.
What is a definition of crude oil?
Mixture
of mostly hydrocarbons
What is the definition of a hydrocarbon?
A compound that contains hydrogen and carbon atoms only.
What is a homologous series?
A group of different compounds with similar structures or functional groups.
What is the general formula for the alkane homologous series?
CnH2n+2
What can be said about alkanes?
They only contain hydrogen and carbon.
All the bonds are single bonds
They are saturated compounds
They have the general formula CnH2n+2
What are the first for alkanes in the homologous series?
Methane - 1
Ethane - 2
Propane - 3
Butane - 4
What are the molecular, structural and empirical formulae of propane?
molecular - C3H8
structural - CH3Ch2CH3
empirical formulae - C3H8
What are the molecular, structural and empirical formulae of butane?
molecular - C4H10
structural - CH3CH2CH2CH3
empirical formulae - C2H5
What is the name of the process by which crude oil is separated?
Fractional distillation
How does fractional distillation work?
The crude oil is heated (to around 350 oC)
As the mixture rises up the fractionating column it cools.
The longer the carbon chain length the higher the boiling point.
Longer chains condense lower down the fractionating column.
Different fractions of the mixture are isolated/removed/produced at different heights in the fractionating column.
What is the trend of boiling and melting point as chain length increases?
The longer the chain the higher the boiling and melting point.
What is meant by the term chain length?
The number of carbon atoms present in single unbroken line of the hydrocarbon.
Why does the boiling and melting point increase as chain length increases?
There are more intermolecular forces between individual molecules as the chain length increases.
What is the trend of flammability as chain length increases?
Flammability decreases as chain length increases.