5: Moulding Flashcards
What is the mechanism of moulding of thermosets?
-Energy (heat, photons, electrons, ect) applied to hardener to create reactive species
-Combined with base resin (monomers/oligomers)
-Exothermic crosslinking reaction creates thermoset polymer
Describe the Kamal-Sourour curing reaction model for thermoset resins
Degree of cure:
-increases with time
-converges to 100% as time tends to infinity
Cure rate:
-increases with degree of cure
-as exothermic reaction rate decreases with increased degree of cure, the rate slows
What does Differential Scanning Calorimetry measure for thermoset resins?
Heat flux to or from the resin while temperature is raised
-First drop step in curve indicates glass transition point
-Later peak shows exothermic heat flux (curing reaction)
-With increasing time the glass transition temperature increases, and rate of curing reaction (exothermic energy) decreases
Explain the thermoset resin processing chain (storage, moulding, curing, post-curing, cooling)
Storage:
-Glassy uncured resin is stored at low temperature (solid resin)
Moulding:
-Temperature increases above glass transition (resin becomes liquid)
Curing:
-Cross-linking reaction forms single molecule polymer network (gelation), cross-linking continues
Post-Curing:
-Additional heat applied
-Higher degree of cross-linking (increasing mechanical properties)
Cooling:
-Rubbery to hard solid as temperature is below glass transition
How does the glass transition temperature vary between the liquid resin and crosslinked resin for thermoset matrices?
-Glass transition of the liquid resin is lower than the crosslinked resin
What are the 3 stages of thermoset resin processing?
A-Stage:
-Early chemical reaction (resin + hardener mixed)
-Liquid at rtp
-used as “out of the bucket” composite manufacturing
B-Stage:
-Intermediate reaction (partially cured but not gelled)
-Tacky at rtp, so frozen for storage to halt the reaction until use
-Used in prepreg laminates (activated by heat)
C-Stage:
-Resin is solidified (finished component
Explain the importance of viscosity for thermoset resins
-Viscosity is correlated to permeability (depends on shear rate, however negligible at low flow rates)
How does viscosity vary during the processing of thermoset resins?
-Decreasing viscosity with increasing temperature
-Increasing viscosity with increasing degree of cure
-Viscosity, degree of cure and temperature all depend on time
-Low viscosity increases wet-out (full impregnation), so set the moulding temperature accordingly
-Can determine an appropriate processing window
How does volumetric shrinkage vary between non-isothermal cure and isothermal cure in thermosets?
-Volumetric shrinkage is greater for non-isothermal cure, resulting in higher residual stresses
-Increased volume change leads to increased risk of deformations
How is temperature controlled for non-isothermal and isothermal thermoset reactions?
Non-isothermal:
-Temperature is not controlled (Temp increases due to exothermic reaction)
Isothermal:
-Temperature is controlled (To reduce volumetric shrinkage)
How does modulus vary with temperature during crosslinking of a thermoset?
-For cured resin; high glass transition temperature is related to high degree of cure
-If temperature is very high then the cross-linked resin will degrade
Why is temperature control during moulding of thermosets important?
-Controls viscosity (ability of wet-out)
-Maximise the degree of crosslinking (improving mechanical properties)
-Minimises the residual stresses
How do stress/strain plots vary for processed thermosets tested at different temperatures?
-Glass transition here is 90 degrees, reflected by the graph (transition from brittle to more ductile as temperature increases)
What is the structure of amorphous thermoplastics?
-Entangled chain molecules
What is the structure of semi-crystalline thermoplastics?
-Chain molecules are partially structured in lamellae
-Amorphous phase between lamellae
-Lamellae arranged in larger structures (spherulites)
Explain the thermoplastic matrix processing chain (storage, moulding, cooling)
Storage:
-stored at room temperature
Moulding:
-Temperature increases above glass transition, formable then liquid (for amorphous)
-Temperature increases above glass transition and melt temperature (higher energy needed to break crystalline phase) (for semi-crystalline)
Cooling:
-Cool below glass transition, hardens (brittle)
Explain the importance of viscosity for thermoplastic matrices
-During moulding, flow depends on viscosity
-No effect of viscosity on degree of cure (as no cross-linking reaction occurs)
-Shear rate dependence is important at high flow velocities (eg. injection moulding)
-Viscosity varies as a function of temperature
How does specific volume vary with temperature for thermoplastics?
-Shrinkage during cooling is greater for semi-crystalline polymers than for amorphous polymers
-Effect of pressure: higher the pressure, the curves shift towards smaller specific volume and higher glass transition temperature
-Thermoplastic heating process is generally reversible (unless quenched)
How does volumetric shrinkage affect the material properties?
-Higher volumetric shrinkage results in large residual stresses, leading to deformations
How does Quenching (rapid cooling) of semi-crystalline thermoplastics affect the structure?
-Reduces the formation of lamellae and therefore remains an amorphous structure after quenching
-Upon reheating, the lamellae can recrystalise
How do mechanical properties of thermoplastics vary with temperature?
Amorphous:
-Hard & brittle below glass transition (high modulus)
-At glass transition, material is “rubbery” (reduction in modulus)
-Liquid above glass transition, therefore can only be used below the glass transition temperature
Semi-Crystalline:
-High modulus below glass transition
-Small reduction in modulus at the glass transition temperature (crystalline phase is unaffected)
-Significant drop in modulus at melt temperature as crystalline phase is disrupted
Why is the control of temperature important during the moulding process of thermoplastics?
-To control viscosity
-Important to control the cooling rate to manage the degree of crystallinity and glass transition temperature
How does controlling of pressure help during the moulding process of thermoplastics?
It helps compensate for shrinkage
Explain the wet-layup open mould process
-Apply release agent to mould surface
-Add layer of reinforcement mat/fabric
-Apply resin (“wet-out”) with a brush/roller
-Consolidate with roller to fully distribute the resin and remove air
-Allow to cure
-Demould and trim
What is a gelcoat in the wet-layup open mould process
Additional resin layer which defines visible part surface properties
What are the advantages of the wet-layup open mould process
-Low investment costs
-Flexible (easy production of most geometries)
What are the disadvantages of the wet-layup open mould process
-Time consuming
-Labour intensive
-Low repeatability of accurate parts (due to user errors)
-Poor dimensional control
-Relatively low fibre volume fractions (can be increased if vacuum bagged after impregnation)
What are the applications of the wet-layup open mould process
-Marine craft
-Large, lightly loaded structures
-Short production runs/one offs
-DIY/hobby applications
-Repairs
Explain the spray-up open mould process
-Mix of thermoset resin (polyester) & fibres (glass), chopped in a hand-held gun, sprayed onto the mould tool
-Left to cure at rtp
-Use of single sided mould (good surface finish on one side)
-100-500 parts per year
What are the advantages of the spray-up open mould process
-Uses roving (low cost material form)
-High deposition rates possible
-Not as labour intensive as wet lay-up
-Can be automated
-Suitable for large components
What are the disadvantages of the spray-up open mould process
-Operator is exposed to styrene emissions
-Low reproducibility (random fibre orientations)
-Poor dimensional control
What are the characteristics of Autoclave processing?
-Heated pressure vessel, isostatic pressure normal to the surface
-Connective heating (temperature control)
-Connections to vacuum pump
What intermediates are typically used in the autoclave process?
-Processing of lay-ups from thermoset prepregs
-B-stage thermoset resin & reinforcements already combined
What are the Autoclave process stages?
-Prepreg laid on tooling surface
-Lay-up enclosed in vacuum bag
-Tooling with lay-up is moved into an autoclave where it is cured
What does applied pressure & vacuum achieve in the Autoclave process?
Lay-up consolidation
What does applied Heating achieve in the Autoclave process?
Induce resin cure
What is the ideal tooling material used in the Autoclave process?
Same material as the laminate (same thermal expansion to prevent warping)
In practise, what is the tooling material used in the Autoclave process?
-Usually metal (high dimensional stability and more durable)
What is the purpose of cut-outs in the tooling used in the Autoclave process?
Allows sufficient airflow to control thermal expansion
How is heat capacity of the tool material important in the Autoclave process?
Affects the rate of heating to cure temperature
What are the components of the vacuum bag in the Autoclave process?
-Vacuum film: seals lay-up from outside air
-Breather: non-woven felt, allows airflow when a vacuum is applied
-Barrier film: prevents resin from permeating into breather
-Bleeder: non-woven felt, absorbs excess resin
-Peel ply: porous fabric (allows excess resin to permeate into the bleeder), prevents sticking between the bleeder and laminate (leaves a textured surface)
-Prepreg lay-up: Resin infused reinforcement fibre
-Mould release: prevents the laminate from bonding to the tool
-Tooling: provides 3D shape for prepreg to conform to
-Sealant tape: seals lay-up from outside air
All components must withstand the curing temperature (high disposable waste process)
Explain the autoclave cycle steps
-Increase temperature to reduce resin viscosity (rate determined by thermal mass (heat capacity) of tooling & lay-up)
-Resin flows at reduced viscosity, vacuum removes trapped air
-Ramp up to cure temperature, pressure increases to compress residual voids
-Hold pressure & temperature until curing is complete
-Cool down to demoulding temperature, vent to ambient pressure
What are the advantages of the Autoclave process?
-High part quality (good mechanical properties due to low void content)
What are the disadvantages of the Autoclave process?
-High cost (high energy, high setup costs and high material costs)
-Labour intensive