5) Enthalpy Change Flashcards

1
Q

Define activation energy

A

The minimum energy required to start a reaction by breaking bonds

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2
Q

What are the standard conditions

A

Temp - 298K (25c)
Pressure - 100KPa
Concentration - 1 moldm-3

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3
Q

What are the two most common exothermic reactions

A
  • Combustion of fuels
  • Respiration
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4
Q

What are the two most common endothermic reactions

A
  • Thermal decomposition
  • Photosynthesis
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5
Q

Define ∆rH

A

The enthalpy change associated with a stated equation

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6
Q

Define ∆rHθ

A

The enthalpy change associated with a stated equation in their standard states under standard conditions

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7
Q

Define ∆fH

A

The enthalpy change when one mole of a compound is made form its elements

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8
Q

Define ∆fHθ

A

The enthalpy change when one mole of a compound is made from its elements in their standard states under standard conditions

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9
Q

Define ∆cH

A

The enthalpy change when one mole of a substance is completely combusted with oxygen

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10
Q

Define ∆cHθ

A

The enthalpy change when one mole of a substance is completely combusted with oxygen under stated conditions

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11
Q

Define ∆neutH

A

The enthalpy change when an aqueous acid is nuterilised by an aqueous base forming one mole of water

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12
Q

Define ∆neutHθ

A

The enthalpy change when an aqueous acid is nuterilised by an aqueous base forming one mole of water under standard conditions

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13
Q

What are the steps to calculate enthalpy change from experimental data

A

1) use Q= -mc∆T
2) Calculate moles of substance burnt
3) use ∆H = Q/n

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14
Q

Where does heat loss occur

A
  • Through the material of the container
  • Through the open top of the container
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15
Q

How can we minimise heat loss

A
  • Use an insulating material
  • Add a lid
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16
Q

Define average bond enthalpy

A

The average enthalpy change when breaking 1 mole of a given type of bond in the molecules of a gaseous species

17
Q

Define Hess’ law

A

The enthalpy change of a reaction is independent of the route taken, providing the intial and final conditions are the same