5. Chemical Reactions Flashcards

1
Q

Chemical reaction/ change

A

-one or more reactants are converted into one or more products

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2
Q

Formula weight

A

-sum of the atomic weights in atomic mass units (amu) of all atoms in the compound’s formula
-used for both ionic and covalent compounds

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3
Q

Molecular weight

A

-term strictly used for covalent compounds

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4
Q

Mole (mol)

A

-the formula weight of a substance expressed in grams
-formal definition: the amount of substance rhat contains as many atoms/molecules/ions as there are atoms in exactly 12g of C-12

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5
Q

Avogadro’s number (#23 sa calcu)

A

-6.02 x 10^(23) formula units per mole
-the amount of any substance that contains as many formula units as the number of atoms in 12 g of C-12

•Amadeo Avogadro
-proposed the concept of mole, but was not able to determine the number experimentally

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6
Q

Molar mass

A

-the mass of one mole of a substance expressed in grams
-formula weight of a compound expressed in grams

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7
Q

Combustion

A

-burning in air

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8
Q

Chemical equation

A

-a representation using chemical formulas of the process that occurs when reactants are converted to products
-written with the coefficients expressed as the lowest set of whole numbers

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9
Q

Stoichiometry

A

-the mass relationships in a chemical reaction
-from Greek “stoicheion” meaning element & “metron” meaning measure

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10
Q

Limiting reagent

A

-the reactant that is used up first
-the reactant that is consumed, leaving an excess of another reagents or reagents unreacted

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11
Q

Percent yield

A

-actual yield divided by the theoretical yield times 100

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12
Q

Actual yield

A

-the mass of product formed in a chemical reaction

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13
Q

Theoretical yield

A

-mass of product that should form in chemical reaction according to the stoichiometry of the balanced equation
-maximum yield

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14
Q

Aqueous solution

A

A solution in which the solvent is water

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15
Q

Dissociation

A

When ionic compound dissolve in water, cation and anions become separated from each other by water molecules

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16
Q

Spectator ion

A

-Ion that appears unchanged on both sides of a chemical equation
-did not participate in the reaction

17
Q

Net ionic equation

A

A chemical equation that does not contain spectator ions; shows only species that actually take part in the reaction

18
Q

Ions in solution react with each other only when one of these four things can happen:

A
  1. Two ions form a solid that is insoluble in water (i.e. AgCl)
  2. Two ions form a gas that escapes from the reaction mixture as bubbles. (i.e. NaHCO3 with HCl to form CO2)
  3. An acid neutralize a base
  4. One of the ions can oxidize another
19
Q

Solubilities of ionic compounds:
Useful generalizations

A
  1. All compounds containing Na+, K+, NH4+ ions are soluble in water.
  2. All nitrates (NO3-) and acetates (CH3COO-) are soluble in water.
  3. Most chloride (Cl-) and sulfates (SO4^(-2)) are soluble in water.
    •Exceptions (insoluble in water): silver chloride (AgCl), lead (II) chloride (PbCl2), mercury (I) chloride (Hg2Cl2), barium sulfate (BaSO4), and lead sulfate (PbSO4)
  4. Most carbonates (CO3^(-2)), phosphates (PO4^(-3)), sulfides (S(-2)), and hydroxides (OH-) are insoluble in water.
    •Exceptions (soluble in water): LiOH, NaOH, KOH, aqueous NH3.
20
Q

Oxidation

A

-loss of electrons; gain of oxygen atoms or the loss of hydrogen atoms

21
Q

Reduction

A

-gain of electrons; loss of oxygen atoms or the gain of hydrogen atoms

22
Q

Oxidation-reduction reaction

A

-involves transfer of electrons from one species to another

23
Q

Oxidizing agent

A

-an entity that accepts electrons in redox reaction

24
Q

Reducing agent

A

-entity that donates electrons in redox reaction

25
Q

Redox reactions that are extremely common:
1. Combustion

A

-compounds or mixtures that are burned are oxidized by oxygen, O2

26
Q

Redox reactions that are extremely common:
2. Respiration

A

-the oxygen in the air we breathe oxidizes carbon-containing compounds in our cells to produce CO2 and H2O

-same lang sa combustion, but at slower and occurs at lower temperature

27
Q

Redox reactions that are extremely common:
3. Rusting

A

-iron is oxidized to a mixture of iron oxides

28
Q

Redox reactions that are extremely common:
4. Bleaching

A

-common bleaches are oxidizing agents
-colored compounds being bleach are usually organic compounds; oxidation converts them to colorless compounds

29
Q

Redox reactions that are extremely common:
5. Batteries

A

-voltaic cells is a device in which electricity is generated feom chemical reaction.

30
Q

Heat of reaction

A

-heat given off or absorbed in a chemical reaction

31
Q

Exothermic reaction

A

-chemical reaction that gives off heat

32
Q

Endothermic reaction

A

-chemical reaction that absorbs heat

33
Q

Heat of combustion

A

-heat given off in a combustion reaction

34
Q

Percent yield

A

(Actual yield / Theoretical yield) x100

35
Q

Oxidation number/ oxidation state

A

The number of charges the atom would have in a molecule (or an ionic
compound) if electrons were transferred completely

36
Q

Ionic equation

A

Shows dissolved species as free ions

37
Q
  1. Redox reactions and 2. Acid-base reactions
A
  1. Transfer of electrons
  2. Transfer of protons