4.22 - Redox Reactions in Group 7 Flashcards

1
Q

In groups 1 and 2, where are reactions the most vigorous?

A

At the bottom

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2
Q

In group 7, where are reactions the most vigorous?

A

At the top

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3
Q

What are the products of these redox reactions?

A

Ionic solids (salts) which are usually white

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4
Q

What does the halogen act as in all of these reactions?

A

An oxidising agent

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5
Q

In terms of electron transfer, what does this mean?

A

Electrons are transferred to the halogen

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6
Q

What is the change in oxidation number for the halogen?

A

0 to -1

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7
Q

What is the change in oxidation number for group 1 and group 2 metals respectively?

A

0 to +1 for group 1, and 0 to +2 for group 2

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8
Q

What can a reactive halogen do?

A

Replace a less reactive halogen from one of its compound

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9
Q

What type of reaction is this?

A

Displacement

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10
Q

What can chlorine displace?

A

Bromine and iodine

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11
Q

What can bromine displace?

A

Iodine

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12
Q

What can iodine displace?

A

Neither chlorine nor bromine

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13
Q

What type of solution do these reactions occur in?

A

Aqueous solutions

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14
Q

Thus, what are reactions indicated by?

A

A colour change

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15
Q

What is a problem with this fact?

A

The colour changes are very discrete, and the colours vary with concentration, making decisions about reactions hard to make

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16
Q

What is a solution to this?

A

Adding an organic solvent such as cyclohexane

17
Q

Why?

A

Because the halogens are more soluble in organic liquids and so the colours are easier to distinguish

18
Q

What broad type of reaction is a displacement reaction?

A

Redox reactions

19
Q

What are the oxidation number changes for the more and less reactive halogens?

A

More reactive: 0 to -1

Less reactive: -1 to 0

20
Q

What is a disproportionation reaction?

A

One in which a single element undergoes both oxidation and reduction

21
Q

What happens when chlorine reacts with water?

A

HCl and HClO are formed

22
Q

What happens when chlorine reacts with cold alkali?

A

Two salts and water are formed

23
Q

Finish the equation: Cl2 + 2NaOH -> … … ….

A

NaCl + NaClO + H2O

24
Q

What happens when chlorine reacts with hot alkali?

A

Two products and water are formed

25
Q

Finish the equation: 3Cl2 + 6NaOH -> … … …

A

5NaCl + NaClO3 + 3H2O