4.2 Isomerism Part 2 Flashcards

1
Q

What are diastereomers?

A

stereoisomers that are not enantiomers; non-superimposable, non-mirror images

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2
Q

What is resolution?

A

the process of separating a racemic mixture since enantiomers have identical chemical and physical properties

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3
Q

What are epimers?

A

subclass of diastereomers that differ in their absolute configuration at a single chiral center

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4
Q

What is an anomer?

A

epimers that form as a result of a ring closure

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5
Q

What is a meso compound?

A

when a molecule containing chiral centers has an internal plane of symmetry

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6
Q

What are geometric isomers?

A

diastereomers that differ in orientation of subsituents around a ring or a double bond

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7
Q

What is a cis molecule?

A

molecule in which two higher priority groups are on the same side

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8
Q

What is a trans molecule?

A

molecule in which two higher priority groups are on opposite sides

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9
Q

What is a Z molecule?

A

two high priority groups are on the same side of a double bond

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10
Q

What is an E molecule?

A

two high priority groups are on opposite sides of a double bond

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