4.1.3 Properties of Alkenes Flashcards
what are alkenes?
unsaturated hydrocarbons containing a carbon carbon double bond comprising a π-bond and a σ-bond
what is a π-bond?
sideways overlap of adjacent p-orbitals above and below the bonding C atoms
what types of bond do alkenes have?
σ and π
what is a σ-bond?
overlap of orbitals directly between the bonding atoms
what type of rotation do alkenes have?
restricted rotation
why do alkenes have restricted rotation?
due to the π-bond (which alkanes do not have)
what bond angle do alkenes have?
120
what shape do alkenes have?
trigonal planar
why do alkenes have this shape?
this shape minimises electron electron repulsion
what homologous series are they apart of?
series with the general formula with CnH2n
what are electrophiles?
species that are electron pair acceptors (attracted to electron dense areas)
why are electrophiles attracted to alkenes?
they are attracted to the highly electron dense double bond
what types of bond make up a carbon carbon double bond?
σ and π
what is a single covalent bond made up of?
σ
what can be used to identify an alkene double bond or other unsaturated compounds?
bromine water