4&14. Chemical bonding and structure Flashcards
Cation
+ve ion
Anion
-ve ion
Polyatomic ion
Ion formed of multiple atoms covalently bonded
Ionic bond
A chemical bond formed between two ions with opposite charges.
Covalent bond
formed by the electrostatic attraction between a shared pair of electrons and the positively charged nuclei.
Shape of molecule with 2 charge centres
Linear 180
Shape of molecule with 3 charge centres
Trigonal planar 120, 180
Shape of molecule with 4 charge centres
Tetrahedral 108.5
London forces
a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.
Hydrogen bonds
formed between a hydrogen atom bonded to a fluorine, oxygen or nitrogen atom and a fluorine, oxygen or nitrogen atom with a pair of lone electrons.
Metalic structure
lattice structure of cations and delocalised outer shell electrons.
Sigma bonds
bonds formed by the direct head-on/end-to-end overlap of atomic orbitals, resulting in electron density concentrated between the nuclei of the bonding atoms.
Pi bonds
bonds formed by the sideways overlap of atomic orbitals, resulting in electron density above and below the plane of the nuclei of the bonding atoms.
Formal charge
the charge each atom would have if all atoms had the same electronegativity and is therefore found by subtracting the total number of dots and lines attached to the atom from the number of valence electrons.
Hybridization =
the mixing of atomic orbitals to form new orbitals that are better arranged for covalent bonding.