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AQA A Level Chemistry > 3.6 Organic Analysis > Flashcards

3.6 Organic Analysis Flashcards

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1
Q

Describe how you would test for alcohols

A

Adding sodium metal to pure alcohol = fizzing as it gives off H2 gas

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2
Q

Describe how you would test for primary, secondary, tertiary alcohols

A
  1. Add 10 drops of alcohol to 2 cm3 of acidified potassium dichromate solution in test tube
  2. Warm mixture gently in hot water bath
  3. Watch for colour change
    1. Primary: Orange solution turns green as aldehyde forms
    2. Secondary: Orange solution turns green as ketone forms
    3. Tertiary: Nothing happens
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3
Q

Describe how you could test for primary alcohol (differentiate it from a secondary alcohol)

A
  1. Add excess alcohol to 2 cm3 of acidified potassium dichromate solution in round bottomed flask
  2. Set up flask as part of distillation apparatus
  3. Gently heat flask
    • Alcohol will be oxidised & product will be distilled off immediately = so you can collect it (if product produced aldehyde, then solution was a primary alcohol)
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4
Q

Name 3 reagents you can use to test for an aldehyde or ketone

A
  1. Fehling’s solution
  2. Benedict’s solution
  3. Tollens’ reagent
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5
Q

Describe a test for an aldehyde or ketone using Fehling’s (or Benedict’s) solution

A
  1. Add 2 cm3 of Fehling’s (or Benedict’s) solution to test tube
  2. Add 5 drops of aldehyde or ketone to test tube
  3. Put test tube in hot water bath to warm it for few minutes
  4. Aldehyde: Blue solution will give brick red precipitate
  5. Ketone: Nothing
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6
Q

Describe a test for an aldehyde or ketone using Tollens’ reagent

A
  1. Put 2 cm3 of 0.1 mol dm-3 silver nitrate solution in test tube
  2. Add few drops of dilute sodium hydroxide to solution
    • Light brown precipitate should form
  3. Add drops of dilute ammonia solution until brown precipitate dissolves completely
  4. Place test tube in a hot water bath and add 10 drops of aldehyde or ketone
  5. Aldehyde: silver mirror forms on walls of test tubes
  6. Ketone: Nothing
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7
Q

Why is a silver mirror produced when Tollens’ reagent is added to an aldehyde?

A

Aldehyde reduced Ag+ ions to silver atoms

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8
Q

Describe the test for alkenes

A
  1. Add 2 cm3 of solution you want to test to test tube
  2. Add 2 cm3 of bromine water to test tube
  3. Shake test tube
  4. Alkene: Solution will go from orange to colourless
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9
Q

Describe the test for carboxylic acids

A
  1. Add 2 cm3 of solution you want to test to test tube
  2. Add 1 small spatula of solid sodium carbonate
  3. If solution begins to fizz, bubble gas that it produces through some limewater in 2nd test tube
  4. Carboxylic Acid: Solution will fizz & CO2 gas produced will turn limewater cloudy
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10
Q

Describe the test for halogenoalkanes

A
  1. Add halogenoalkane (R—X) and sodium hydroxide to test tube
  2. Warm it by placing it in hot water bath
  3. Add dilute nitric acid and silver nitrate solution to test tube to acidify its contents
  4. Halogenoalkane: Precipitate of AgX
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11
Q

What is mass spectrometry used for?

A

To find Mr of compound

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12
Q

Molecular ion (M+) is formed when…

A

a molecule loses an electron

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13
Q

M+ produces ____ _____ ____ on mass spectrum of compound

A

molecular ion peak

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14
Q

Mass/charge (m/z) value of molecular ion peak = …

A

molecular mass of compound

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15
Q
A
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16
Q

What does high resolution mass spectrometry measure?

A

Measure atomic and molecular masses extremely accurately

17
Q

What is high resolution mass spectrometry used for?

A

Identifying compounds that have same Mr when rounded to nearest whole number

18
Q

Describe how infrared spectroscopy works

A
  1. Beam of IR radiation passed through sample of chemical
  2. IR radiation absorbed by covalent bonds in molecules = ↑ vibrational energy
    1. Bonds between different atoms absorb different frequencies of IR radiation
    2. Bonds in different places in molecules absorb different frequencies too (e.g. O-H group in alcohol and O-H in carboxylic acid absorb different frequencies)
19
Q

What does an infrared spectrometer produce & what does this show?

A

Infrared spectrometer produces graph that shows what frequencies of radiation molecules are absorbing

20
Q

What can a graph produced by an infrared spectrometer be used for?

A

To identify functional groups in molecule

21
Q

The fingerprint region is between ______ and ______

A

500 cm-1 and 1500cm-1

22
Q

Fingerprint region is _____ to a particular compound

A

Unique

23
Q

Describe how you can use the fingerprint region to identify a molecule

A
  • Can use computer database to check this region of unknown compound’s IR spectrum against known compounds
  • If it matches one of them = know what molecule it is
24
Q

Infrared spectroscopy can also be used to find out….

A

how pure compound is & identify any impurities

25
Q

Impurities produce …. in infrared spectroscopy

A

extra peaks in fingerprint region

26
Q

Describe how infrared radiation absorption is linked to global warming

A
  1. Some electromagnetic radiation emitted by Sun reaches Earth and is absorbed
    • Earth re-emits some of its infrared radiation (heat)
  2. Molecules of greenhouse gases (CO2, CH4, water vapour) in atmosphere absorb IR radiation (it’s bonds of these molcules that absorb it)
    • & re-emit some of it back towards Earth = keeps us warm
    • Called greenhouse effect
  3. Human activities, burning fossil fuels & leaving rubbish to rot in landfill sites, caused rise in greenhouse gas concentrations
  4. Means more heat being trapped and Earth getting warmer = global warming
27
Q

Infra-red spectrum for ethanoic acid

Describe the 2 main peaks

A
  • Board peak at 2500 – 3000 cm-1 shows O-H bond (in carboxylic acid)
  • Sharp peak at 1680 – 1750 cm-1 shows C=O

(carboxylic acid = 2 peaks)

28
Q

State the homologous series shown by this infra-red spectrum

A

Alcohol

(Acid’s peak is boarder than alcohol)

29
Q

State the homologous series shown by this infra-red spectrum

A

Aldehyde

AQA A Level Chemistry (36 decks)

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