3.4 Equilibiria Flashcards
Dynamic equilibrium
In a closed system, reversible reactions attain a state of dynamic equilibrium when the rate of forward and reverse reactions are equal
Equilibrium
At equilibrium, the concentrations of reactants and products remain constant, but are rarely equal
How to maximise profits using equilibrium?
To maximise profits chemists employ strategies to move the position of equilibrium in favour of the products
Effect of catalyst on equilibrium
The addition of a catalyst increases the rates of the forward and reverse reactions equally. The catalyst increases the rate at which equilibrium is achieved but does not affect the position of equilibrium
Effect of concentration on equilibrium
A + B = C + D (reversible reaction)
Increase concentration of reactants ( A + B ) either by removing products or adding reactants will cause the forward reaction to increase therefore more product (C + D) will be produced
Increasing the concentration of products (C +D) either by removing reactants or adding products will result in the rate of the reverse reaction increasing therefore producing more reactants (A + B)
Effect of temperature on equilibrium
Increasing the temperature causes the equilibrium to shift and favour the endothermic reaction
Decreasing the temperature causes the equilibrium to shift and favour the exothermic reaction
Effect of pressure on equilibrium
Increasing the pressure causes the equilibrium to shift and favour the side it’s the least gas moles.
Decreasing the pressure causes the equilibrium to shift and favour the side with the most gas moles .
If there are no gas moles or equal gas moles on each side then pressure will have no effect