33 Flashcards

1
Q

Identify

A

QUATERNARY AMONIUM BASE

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2
Q
A

1-hydroxi, 2-methyl- propane

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3
Q
A

Methyl-amine

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4
Q
A

Dimethyl-amine

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5
Q
A

Trimethyl-amine

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6
Q
A

PYRIDINE

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7
Q
A

PYRIDAZINE

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8
Q
A

PYRIMIDINE

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9
Q
A

PYRAZINE

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10
Q

The lone pair of the N is less prominent than in amines

WHY?

A

because the aromatic system steals an electron from the nitrogen. Very weak bases.

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11
Q
A

PYRROLE

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12
Q
A

IMIDAZOLE

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13
Q

ANILINE

A
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14
Q

Describe aryl-amines (lone pair, NH bonds)

A

The lone pair of the N is partially lost, because it tends to conjugate with the aromatic system.

The N-H bonds are more polarized due to the partially lost lone pair.

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15
Q

amides develop from (1)__ and (2)___ or (3)___

A

1 - amines
2 - esters
3 - acid anhydrides

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16
Q
A

CARBAMIC ACID
-> MONOAMIDE OF CARBONIC ACID
UNSTABLE

17
Q
A

URETHANE:
-> ESTER OF CARBAMIC ACID
A CARBAMATE

18
Q
A

UREA, CARBAMIDE:

DIAMIDE OF CARBONIC ACID NEITHER ACIDIC NOR BASIC

19
Q
A

Imine

20
Q

Is imine a strong base?

A

Yes

21
Q
A

2,4-DINITRO-PHENOL

22
Q
A

DINITRO-FLUOROBENZENE