3.2.6 New Aqueous Ions Flashcards

1
Q

Write a chemical equation for the reaction between [Fe(H2O)6]2+ and NaOH

A

[Fe(H2O)6]2++ 2OH⁻→ Fe(H2O)4(OH)2+ 2H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Write a chemical equation for the reaction between [Fe(H2O)6]2+ and NH3

A

[Fe(H2O)6]2++ 2NH3→ Fe(H2O)4(OH)2+ 2NH4+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Write a chemical equation for the reaction between [Fe(H2O)6]2+ and Na2CO3

A

[Fe(H2O)6]2+ + CO32⁻ → FeCO3+ 6H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Write a chemical equation for the reaction between [Fe(H2O)6]3+ and NaOH

A

[Fe(H2O)6]3++ 3OH⁻→ Fe(H2O)3(OH)3+ 3H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Write a chemical equation for the reaction between [Fe(H2O)6]3+ and NH3

A

[Fe(H2O)6]3++ 3NH3→ Fe(H2O)3(OH)3+ 3NH4+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Write a chemical equation for the reaction between [Fe(H2O)6]3+ and Na2CO3

A

2[Fe(H2O)6]3++ 3CO32⁻→ 2Fe(H2O)3(OH)3+ 3CO2+ 3H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Write a chemical equation for the reaction between [Al(H2O)6]3+ and NaOH

A

[Al(H2O)6]3++ 3OH⁻→ Al(H2O)3(OH)3+ 3H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Write a chemical equation for the reaction between [Al(H2O)6]3+ and excess NaOH

A

[Al(H2O)6]3++ 4OH⁻→ [Al(OH)4]⁻+ 6H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Write a chemical equation for the reaction between Al(H2O)3(OH)3 and excess NaOH

A

Al(H2O)3(OH)3+ OH⁻ → [Al(OH)4]⁻+ 3H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Write a chemical equation for the reaction between [A(H2O)6]3+ and NH3

A

[Al(H2O)6]3++ 3NH3→ Al(H2O)3(OH)3+ 3NH4+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Write a chemical equation for the reaction between [Al(H2O)6]3+ and Na2CO3

A

2[Al(H2O)6]3+ + 3CO32⁻→ 2Al(H2O)3(OH)3+ 3H2O + 3CO2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Write a chemical equation for the reaction between [Cu(H2O)6]2+ and NaOH

A

[Cu(H2O)6]2++ 2OH⁻→ Cu(H2O)4(OH)2+ 2H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Write a chemical equation for the reaction between [Cu(H2O)6]2+ and NH3

A

[Cu(H2O)6]2++ 2NH3→ Cu(H2O)4(OH)2+ 2NH4+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Write a chemical equation for the reaction between [Cu(H2O)6]2+ and excess NH3

A

[Cu(H2O)6]2++ 4NH3→ [Cu(H2O)2(NH3)4]2+ + 4H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Write a chemical equation for the reaction between Cu(H2O)4(OH)2 and excess NH3

A

Cu(H2O)4(OH)2+ 4NH3→ [Cu(H2O)2(NH3)4]2+ + 2H2O + 2OH⁻

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Write a chemical equation for the reaction between [Cu(H2O)6]2+ and Na2CO3

A

[Cu(H2O)6]2+ + CO32⁻ → CuCO3+ 6H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Write a chemical equation for the reaction between [Cu(H2O)6]2+ and HCl

A

[Cu(H2O)6]2+ + 4Cl⁻ → [CuCl4]2⁻+ 6H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Which aqueous-ion solutions are the most acidic?

A

Solutions of [Fe(H2O)6]3+ and [Al(H2O)6]3+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

Which aqueous-ion solutions are the least acidic?

A

Solutions of [Fe(H2O)6]2+ and [Cu(H2O)6]2+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Why are solutions of [Al(H2O)6]3+ acidic?

A

Al3+ is small and has a high charge. Al3+ polarises the O−H bonds in the H2O ligands, which weakens the O−H bonds (and allows H+ to dissociate)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Why are solutions of [Fe(H2O)6]3+ acidic?

A

Fe3+ is small and has a high charge. Fe3+ polarises the O−H bonds in the H2O ligands, which weakens the O−H bonds (and allows H+ to dissociate)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

Why are solutions of [Al(H2O)6]3+ and [Fe(H2O)6]3+ more acidic than solutions of [CuH2O)6]2+ and [Fe(H2O)6]2+?

A

Al3+ and Fe3+ are smaller and have a higher charge than Cu2+ and Fe2+. Al3+ and Fe3+ polarise the water ligands more than Cu2+ and Fe2+, so the weaken the O−H bonds more (and dissociate more H+)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

What coulour is aqueous [Fe(H2O)6]2+

A

Green solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

What is observed when NaOH is added to aqueous [Fe(H2O)6]2+?

A

Green solution forms a green precipitate (goes brown on standing in air)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
What is observed when excess NaOH is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate. No further change
26
What is the formula of the precipitate formed when NaOH is added to aqueous [Fe(H2O)6]2+?
Fe(H2O)4(OH)2
27
What is observed when NH3 is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate (goes brown on standing in air)
28
What is observed when excess NH3 is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate. No further change
29
What is the formula of the precipitate formed when NH3 is added to aqueous [Fe(H2O)6]2+?
Fe(H2O)4(OH)2
30
What is observed when Na2CO3 is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate
31
What is the formula of the precipitate formed when Na2CO3 is added to aqueous [Fe(H2O)6]2+?
FeCO3
32
What reactants can be used to produce Fe(H2O)4(OH)2?
[Fe(H2O)6]2+ reacted with NaOH or NH3
33
What reactants can be used to produce FeCO3?
[Fe(H2O)6]2+ reacted with Na2CO3
34
Describe the appearance of Fe(H2O)4(OH)2
Green precipitate (goes brown on standing in air)
35
Describe the appearance of FeCO3
Green precipitate
36
What coulour is aqueous [Fe(H2O)6]3+
Purple solution (but looks brown due to some dissociation into [Fe(H2O)5(OH)]2+)
37
What is observed when NaOH is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate
38
What is observed when excess NaOH is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate. No further change
39
What is the formula of the precipitate formed when NaOH is added to aqueous [Fe(H2O)6]3+?
Fe(H2O)3(OH)3
40
What is observed when NH3 is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate
41
What is observed when excess NH3 is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate. No further change
42
What is the formula of the precipitate formed when NH3 is added to aqueous [Fe(H2O)6]3+?
Fe(H2O)3(OH)3
43
What is observed when Na2CO3 is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate and effervescence (CO2 is released)
44
What is the formula of the precipitate formed when Na2CO3 is added to aqueous [Fe(H2O)6]3+?
Fe(H2O)3(OH)3
45
What reactants can be used to produce Fe(H2O)3(OH)3?
[Fe(H2O)6]3+ reacted with NaOH, NH3, or Na2CO3
46
Describe the appearance of Fe(H2O)3(OH)3
Brown precipitate
47
What coulour is aqueous [Al(H2O)6]3+?
Colourless solution
48
What is observed when NaOH is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate
49
What is observed when excess NaOH is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate that then dissolves to form a colourless solution
50
What is the formula of the precipitate formed when NaOH is added to aqueous [Al(H2O)6]3+?
Al(H2O)3(OH)3
51
What is the formula of the complex ion formed when excess NaOH is added to aqueous [Al(H2O)6]3+?
[Al(OH)4]⁻
52
What is observed when NH3 is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate
53
What is observed when excess NH3 is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate. No further change
54
What is the formula of the precipitate formed when NH3 is added to aqueous [Al(H2O)6]3+?
Al(H2O)3(OH)3
55
What is observed when Na2CO3 is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate and effervescence (CO2 is released)
56
What is the formula of the precipitate formed when Na2CO3 is added to aqueous [Al(H2O)6]3+?
Al(H2O)3(OH)3
57
What reactants can be used to produce Al(H2O)3(OH)3?
[Al(H2O)6]3+ reacted with NaOH, NH3 (not in excess), or Na2CO3
58
What reactants can be used to produce aqueous [Al(OH)4]⁻?
[Al(H2O)6]3+ reacted with excess NH3
59
Describe the appearance of Al(H2O)3(OH)3
White precipitate
60
Describe the appearance of aqueous [Al(OH)4]⁻
Coourless solution
61
What coulour is aqueous [Cu(H2O)6]2+?
Blue solution
62
What is observed when NaOH is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a blue precipitate
63
What is observed when excess NaOH is added to aqueous [Cu(H2O)6]2+?
Blue solution froms a blue precipitate. No further change
64
What is the formula of the precipitate formed when NaOH is added to aqueous [Cu(H2O)6]2+?
Cu(H2O)4(OH)2
65
What is observed when NH3 is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a blue precipitate
66
What is observed when excess NH3 is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a blue precipitate which then forms a deep blue solution
67
What is the formula of the precipitate formed when NH3 is added to aqueous [Cu(H2O)6]2+?
Cu(H2O)4(OH)2
68
What is the formula of the complex ion formed when excess NH3 is added to aqueous [Cu(H2O)6]2+?
[Cu(H2O)2(NH3)4]2+
69
What is observed when Na2CO3 is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a blue-green precipitate
70
What is the formula of the precipitate formed when Na2CO3 is added to aqueous [Cu(H2O)6]2+?
CuCO3
71
What is observed when HCl is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a yellow-green solution
72
What is the formula of the complex ion formed when HCl is added to aqueous [Cu(H2O)6]2+?
[CuCl4]2⁻
73
What reactants can be used to produce Cu(H2O)4(OH)2?
[Cu(H2O)6]2+ reacted with NaOH or NH3 (not in excess)
74
What reactants can be used to produce aqueous [Cu(H2O)2(NH3)4]2+?
[Cu(H2O)6]2+ reacted with excess NH3
75
What reactants can be used to produce CuCO3?
[Cu(H2O)6]2+ reacted with Na2CO3
76
What reactants can be used to produce aqueous [CuCl4]2⁻?
[Cu(H2O)6]2+ reacted with HCl
77
Describe the appearance of Cu(H2O)4(OH)2
Blue precipitate
78
Describe the appearance of aqueous [Cu(H2O)2(NH3)4]2+
Deep blue solution
79
Describe the appearance of CuCO3
Blue-green precipitate
80
Describe the appearance of aqueous [CuCl4]2⁻
Yellow-green solution