3.2.1 Periodicity Flashcards

1
Q

Structure of the periodic table

A

Group = vertical
Period = horizontal

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2
Q

Periodicity definition

A

Study of repeated trends in a period
pattern in properties of an element across a period

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3
Q

Atomic radius trends on the periodic table

A

Atomic radius decreases along a period
As nuclear charge increases and shielding remains constant

Atomic radius increases down a group
As shielding increases which reduces the attraction

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4
Q

Ionisation energy trends on the periodic table

A

Ionisation energy along a period increases
As the ar is is decreasing and the nuclear charge is increasing
So are held strongly together so more energy is needed to separate

Down a group it decreases
As nuclear attraction decreases as shielding increases less energy needed

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5
Q

Melting point is period 3

A

increases till si
then drops down for p
then increases up to s
then decreases to cl and ar

cl and p lower than na
s higher than na

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6
Q

Reasons for the different melting points in group 3

A

Na,mg.al = metal sso have metallic bonding. Increase across as greater positively charged ions. More e released - so electrostatic forces increase

Si - giant covalent - string covalent bonding
P,s,cl - simple covalent - weak van der waals
Ar - very stable as is a full outer shell has weak van der waals

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7
Q

periodic table

A

list of all known elements in order of increasing atomic mass

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8
Q

lanthandides and actinides

A

lanthadides - top
are metals which are not often enocountered

acetinindes radiactove metals found in trace quantities

make up f block

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9
Q

trend period 3 react to form

A

group 1,2,3 - giant ionic compounds - loose there outer electrons to form ionic compound

group 4-si
4 electrons in outer shell meaning 4 covalent bonds - giant covalent

group5,6,7
covalent compounds or ionic compounds

group 0 - full outer shell - uncreative

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10
Q

non metals melting point

A

vander walls - for molecular
vander walls effected by the number of electrons and how closely they pack together

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11
Q

bonding period 3

A

na,mg - meatalic bonding
si - macromolecular
p,s,cl - simple molecular
ar - nobal gas

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12
Q

metals melting point

A

effected by the strength of the metallic bonding

  • depends on the sea of delocalized electrons
  • charge of the ion
  • meaning stronger attraction in lattice
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13
Q

how to measure atomic radius

A

can only be measured by 2 atoms -has no clear point the electron density drops to 0

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14
Q

ionisation elegy anomalies

A

AL looses from a higher energy level 3p not 3s
s - outer most electron is paired in p orbital meaning easily removed

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15
Q

why sulfur has a higher melting point than phosphorus

A

becuase s8 bigger than p4 - larger molecule

meaning more vnader vaal

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16
Q

period 3 highest second ionisation energy

A

na
Electron (removed) from the 2nd shell / 2p (orbital)

17
Q

why ionisation energy is endothermic

A

energy needed to overcome the attraction
between the (negative) electron and the (positive)
nucleus or protons

18
Q

why second ionization energy is higher than first

A

(More energy to) remove an electron from a (more)
positive ion / cation