3.1.2 Flashcards
What is enthalpy?
the heat energy stored in a chemical system
How do we measure enthlpy?
MEASURE energy released to the surroundings or absorbed
What is the standard pressure?
100kPa
What is the standard temp?
298K or 25 degrees
What is the standard concentration?
1 Mol dm-3
What is the standard state of C?
solid
What is the standard enthalpy change of combustion?
enthalpy change when 1 mole of a substance reacts completely with oxygen under standard conditions
What is the standard enthalpy change of formation?
enthalpy change when 1 mole of a substance is formed from it’s elements under standard conditions
Why are experimental values for the standard enthalpy of combustion lower than data book values?
heat is lost despite insulation - not all energy transferred to water
chance of incomplete combustion
non standard conditions
What is enthalpy change of neutralisation?
enthalpy change when an aqueous acid neutralises an aqueous base to form 1 mole of water
What is Hess’s law?
more than 1 route possible
initial and final substances are the same
overall enthalpy change is the same
What is bond enthalpy?
when 1 mole of a covalent bond is broken in gaseous conditions
Why can bon breaking be exothermic sometimes?
more energy released by bond breaking than bond making