3.1.1- Periodicity Flashcards

1
Q

How is the periodic table arranged?

A

Based on increasing proton number

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2
Q

What do the periods show?

A

Repeating trends in physical and chemical properties

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3
Q

What do groups show?

A

Elements with similar chemical properties

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4
Q

What happens to atomic radius along a period?

A

Decreases due to increased nuclear charge

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5
Q

What happens to atomic radius down a group?

A

Increases as increased shielding which reduces nuclear attraction

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6
Q

What is first ionisation energy?

A

The minimum energy required to remove one mole of electrons from one mole of atoms in a gaseous state

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7
Q

What happens to ionisation energy as you go along a period?

A

Increases due to decreasing atomic radius and greater electrostatic forces of attraction

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8
Q

What happens to ionisation energy as you go down a group?

A

Decreases due to increasing atomic radius and electron shielding which reduces electrostatic forces of attraction

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9
Q

What about ionisation energies indicates what group an element is in?

A

A large jump between ionisation energies

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10
Q

What are the exceptions to an increasing trend of ionisation energy in period 2?

A

Boron and oxygen

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11
Q

Why is boron an exception?

A

It has a lower ionisation energy due to the energy difference between the 2s and 2p sub-shells as the electron is being removed from a higher energy level that is further from the nucleus

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12
Q

Why is oxygen an exception?

A

Due to repulsion within the 2p orbital when two electrons with opposite spins are placed in the same orbital, so electrons can be removed more easily

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13
Q

What are the exceptions of ionisation energies increasing in period 3?

A

Aluminium and sulfur

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14
Q

What is a metallic bond?

A

Strong electrostatic attraction between cations and delocalised electrons

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15
Q

What are the properties of metallic properties?

A

-good conductors
-malleable as layers of ions can slide over each other
-high mp

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16
Q

What is diamond?

A

A macro molecular structure made up of carbon atoms, each of which are bonded to 4 further carbon atoms, providing a rigid structure

17
Q

What is graphite?

A

A macro molecular structure where each carbon is bonded to three other carbon atoms in flat sheets, so there is one delocalised electron per carbon atom so can conduct electricity

18
Q

Why is graphite a good lubricant?

A

Has weak London forces between layers, which allows layers to slide over each other

19
Q

What is graphene?

A

Consists of 2D sheets of graphite that are one atom thick. The sheets are formed of hexagonal carbon rings that create a very strong, rigid material that is lightweight and conducts electricity

20
Q

What is the trend of melting points along period 2?

A

Increases up to carbon, then is very low again

21
Q

What is the trend of melting points along period 3?

A

Increases, then shoots up for silicon as it’s macro molecular, then decreases again, slightly peaking at sulphur, then decreasing again