3. Nuclear Masses Flashcards
Z
- proton number / atomic number
- determines the place of an element in the periodic table
N
-neutron number
A
-mass number or nucleon number
A = Z + N
Nuclide
Definition
-a specific set of numbers Z, N, A determines a nuclide
Isobar
Definition
-nuclides with the same mass number, A, are isobars
Isotope
Definition
-nuclides with the same proton/atomic number, Z, are isotopes
Isotone
Definition
-nuclides with the same neutron number, N, are isotones
Why is this formula for nuclear mass incorrect?
M = Zmp + Nmn
-due to the strong force, we cannot simply calculate the nuclear mass in this way as the binding energy makes a large contribution
Nuclide Map
- a plot of neutron number N on the x axis and proton number Z on the y axis
- there is a line that is most stable and a region of lower stability but where nuclides can still exist, this is known as the valley of stability
- outside of this nuclides are so unstable that they cannot exist
- to decay a nuclide needs to transition to one of slightly lower mass close to it on the nuclide map
- i.e. if a nuclide is surrounded by higher mass nuclides on the map then it won’t decay
Binding Energy
Definition
-the energy required to release a nucleon from the nucleus
Eb = ∫ F ds
-where the integral is taken from the nuclear radius r to infinity
Nuclear Mass
Equation
M = Zmp + Nmn - Eb/c²
Binding Energy vs Ionisation Energy
- Eb accounts for around 1% of the nuclear mass
- comparing with the analogous electron ionisation energy:
- electron ionisation energy accounts for only ~10^(-9)% of the atomic mass
- it is clear that binding energy contributes a much more significant percentage and whilst we may be able to omit ionisation energy from atomic mass calculations, we must account for binding energy in nuclear mass calculations
Mass Defect
m = Eb / c²
Finding Binding Energy Experimentally
- found by measuring nuclear mass
- atomic masses may be measured by deflecting ions in electric and magnetic fields
- an ion in such a field follows a curved path with a particular radius of curvature
- |E gives re which is related to kinetic energy and |V give rmag which is related to momentum, from these we can determine mass
Mass Spectrometry
- particles pass through electric and magnetic fields on a curved path
- the radius of curvature is determined by energy for the electric field and momentum for the magnetic field
- the fields are tuned so that only particles of a particular mass will reach the detector