1. History Flashcards

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1
Q

Plum-Pudding Model

A
  • prior to the discovery of the nucleus, the most widely accepted model of the atom was the plum-pudding model
  • electrons embedded in a diffuse cloud of positive charge
  • a reasonably successful model though it failed to explain emission spectra
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2
Q

Rutherford Experiment

Description

A
  • alpha particles (helium nuceli) fired at a thin piece of gold foil
  • deflections were observed using a fluorescent screen
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3
Q

Rutherford Experiment

Conservation of Energy

A

-consider the scattering process of a moving alpha particle off a stationary target:
1/2 mα vo² = 1/2mα vα² + 1/2mt vt²
-rearranging:
vo² = vα² + mt/mα * vt²

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4
Q

Rutherford Experiment

Conservation of Momentum

A

-consider the scattering process of a moving alpha particle off a stationary target:
vo = mαvα + mt*vt

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5
Q

Rutherford Experiment

Combining Conservations of Energy and Momentum

A

vt² (1 - mt/mα) = 2vα . vt =

2 |vα| |vt| cosθ

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6
Q

Rutherford Experiment

target mass less than α mass

A

-if the target mass is much less than the α mass (e.g. α scattered off an electron), mt/mα«1 then:
vt² ≈ 2 |vα| |vt| cosθ
-this makes cosθ > 0 (θ

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7
Q

Rutherford Experiment

target mass greater than α mass

A

-if the target mass is much greater than the α particle mass, the α particle can recoil sharply backwards in the direction it originally came from

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8
Q

Rutherford Experiment

Observations and Implications

A
  • Rutherford found that the α particles occasionally recoiled from the gold foil
  • the plum pudding model was unable to account for this
  • instead we need an atomic model with high-mass objects
  • since the large angle deflections were rare, the heavy object must be small
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9
Q

Nuclear Model of the Atom

A
  • heavy dense nucleus
  • electrons in large orbitals
  • mostly empty space
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10
Q

Impact Parameter

A
  • consider an α particles trajectory as it collides with a gold nucleus
  • the perpendicular displacement of the initial trajectory from perfect head-on collision is called the impact parameter, b
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11
Q

Large b

A

-for larger b, the Coulomb repulsion is low

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12
Q

Small b

A

-for very small b, the α particle moves through the nucleus and is therefore subject to a smaller effective charge

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13
Q

b of order of the nuclear radius

A

-for b of the order of the gold nucleus’s radius, the deflection is maximum

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14
Q

Calculating Deflection

Approximation

A

-in an approximate calculation we can take the Coulomb repulsion to act in a direction perpendicular to the initial trajectory, and only over a distance b
-so for an α particle velocity v, we assume the force only acts for a time:
Δt = b/v

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15
Q

Calculating Deflection

Coulomb Force

A

F = 1/4πεo * (2e)(Ze)/b²

  • where 2e is the charge on the α particle
  • and Ze is the charge on the gold nucleus
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16
Q

Calculating Deflection

Change in Momentum

A
-the deflection angle θ in radians is approximately
θ = Δp/p , but F = Δp/Δt
so:
θ = 1/4πεo * 2Ze²/b² * b/v * 1/mv
-rearrange for b:
b =  1/4πεo * 2Ze²/mv² * 1/θ
17
Q

Calculating Deflection

Nuclear Radius

A

-from the data we can see that maximum deflection is of order 1 radian
-subbing in the other numbers we get:
B = R ≈ 10^(-14) m
-note that this is much smaller than the atomic radius

18
Q

Rutherford Scattering Formula

A
N(θ) = (1/4πεo)² * NiρLZ²e^4/4r²E²sin^4(θ/2)
-for point-particle targets where:
N(θ) = no.of particles scattered at θ
Ni = number of incident particles 
ρ = density of target
L = target thickness
r = target-to-deflector distance
E = kinetic energy of α particle
19
Q

When does the Rutherford scattering formula fail?

A
  • at sufficiently high energy levels the α particles will penetrate the nucleus
  • at this point, the nucleus no longer behaves as a point-particle and the Rutherford formula fails
20
Q

Rutherford Scattering Formula and Protons

A
  • a similar breakdown of the Rutherford formula occurs with protons as with nuclei
  • this demonstrates that protons are not fundamental
21
Q

Strong Nuclear Force

A
  • since Rnucleus ≈ 10^(-15)-10^(-14) m and all the atom’s positive charge is contained in such a small region, there must be a huge attractive force to overcome the Coulomb repulsion
  • this is the strong nuclear force
  • the strong force is only a short-range force and its effects are not seen at scales larger than the nuclear radius
22
Q

The Strong Force and the Rutherford Scattering Experiment

A
  • the strong force is also present in α particles and this can confuse matters in the Rutherford scattering experiment
  • for this reason the most accurate versions of the experiment use electrons instead as they are not subject to the strong nuclear force