1. History Flashcards
Plum-Pudding Model
- prior to the discovery of the nucleus, the most widely accepted model of the atom was the plum-pudding model
- electrons embedded in a diffuse cloud of positive charge
- a reasonably successful model though it failed to explain emission spectra
Rutherford Experiment
Description
- alpha particles (helium nuceli) fired at a thin piece of gold foil
- deflections were observed using a fluorescent screen
Rutherford Experiment
Conservation of Energy
-consider the scattering process of a moving alpha particle off a stationary target:
1/2 mα vo² = 1/2mα vα² + 1/2mt vt²
-rearranging:
vo² = vα² + mt/mα * vt²
Rutherford Experiment
Conservation of Momentum
-consider the scattering process of a moving alpha particle off a stationary target:
mαvo = mαvα + mt*vt
Rutherford Experiment
Combining Conservations of Energy and Momentum
vt² (1 - mt/mα) = 2vα . vt =
2 |vα| |vt| cosθ
Rutherford Experiment
target mass less than α mass
-if the target mass is much less than the α mass (e.g. α scattered off an electron), mt/mα«1 then:
vt² ≈ 2 |vα| |vt| cosθ
-this makes cosθ > 0 (θ
Rutherford Experiment
target mass greater than α mass
-if the target mass is much greater than the α particle mass, the α particle can recoil sharply backwards in the direction it originally came from
Rutherford Experiment
Observations and Implications
- Rutherford found that the α particles occasionally recoiled from the gold foil
- the plum pudding model was unable to account for this
- instead we need an atomic model with high-mass objects
- since the large angle deflections were rare, the heavy object must be small
Nuclear Model of the Atom
- heavy dense nucleus
- electrons in large orbitals
- mostly empty space
Impact Parameter
- consider an α particles trajectory as it collides with a gold nucleus
- the perpendicular displacement of the initial trajectory from perfect head-on collision is called the impact parameter, b
Large b
-for larger b, the Coulomb repulsion is low
Small b
-for very small b, the α particle moves through the nucleus and is therefore subject to a smaller effective charge
b of order of the nuclear radius
-for b of the order of the gold nucleus’s radius, the deflection is maximum
Calculating Deflection
Approximation
-in an approximate calculation we can take the Coulomb repulsion to act in a direction perpendicular to the initial trajectory, and only over a distance b
-so for an α particle velocity v, we assume the force only acts for a time:
Δt = b/v
Calculating Deflection
Coulomb Force
F = 1/4πεo * (2e)(Ze)/b²
- where 2e is the charge on the α particle
- and Ze is the charge on the gold nucleus