3. Equilibrium Flashcards
What is the relationship between d(G) and K
D(G) = -RTlnK
How do you convert pressures to concentrations?
P(A) = [A]RT
What does a large value of Kc mean
The eqm is on the product side
What does a small value of Kc mean
The equilibrium is on the reactant side
If Qc>Kc…?
reactants will tend to form
If Qc
Products will tend to form
What is the general relationship between Kp and Kc?
Kp = Kc(RT)^d(n)
What is heterogenous equilibrium?
Components exist in different physical forms (one or more components are of different phases than the others)
What is Le chatelier’s principle?
If an outside influence upsets an equilibrium, the system undergoes a change in a direction that counteracts the disturbing influence and if possible, returns the system to equilibrium.
How can the K value at a specified temperature be calculated if the value of K at another temperature is known?
The Van’t hoff equation
.lnK(T1)-lnK(T2) = d(H)/R(1/T1- 1/T2)
What is the equation for oxygen transport?
Hb4(aq) + 4O2(aq) <=>Hb4O8