3 - Bonding Flashcards

1
Q

What are the three types of inter-atomic bonding

A

Covalent - Between two non-metals

Metallic - Between two Metals

Ionic - Between a metal and a non-metal

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2
Q

What are the main features of Ionic bonding

A

Forming salts, the metal will donate an electron to the non-metal, forming two ions, normally both with the electronic structure of noble gases, which are attracted to each other by electrostatic forces, they form solids with lattice structures at room temperature with very high melting points, and are often conductive in solution and when liquid

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3
Q

What are the main features of Covalent bonding

A

Two non metals will share electrons, forming single, double and triple bonds, allowing the two atoms to obtain noble electronic structures, in simple Covalent molecules, they have low melting and boiling points, and with giant, high melting and boiling points.

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4
Q

What is a co-ordinate or dative bond

A

one atom provides both electrons in the Covalent bond

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5
Q

What are the main features of Metallic bonding

A

the outer shell electrons of each metal atom will delocalise, forming a ‘sea of electrons’ with, due to the electrostatic attraction, binds the atoms together, whilst also alowing the transfer of charge and energy easily through them, and also gives them the properties of being strong, malleable, ductile, and having high melting points.

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6
Q

What is the definition of electronegativity

A

Electronegativity is the power of an atom to attract the electron density in a covalent bond towards itself.

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7
Q

What is the trend in electronegativity

A

It increases as you go up and right in the periodic table

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8
Q

What is polarity

A

When one of the atoms in a covalent bond has a greater share of the electron density, it causes that atom to be partially negative, and the other partially positive, which will act as if they were magnets

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9
Q

What are the three types of inter-molecular forces from weakest to strongest

A

Van der Waals forces - where there is momentary charge displacement causes momentary attraction between different molecules

Dipole-dipole forces - where the Molecule has overall polarity, so therefore they line up and form stronger inter-molecular bonds that normal

Hydrogen bond - a form of Dipole-dipole, where there is a hydrogen involved, causing a far stronger bond

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10
Q

What is electron pair repulsion theory

A

Each pair of electrons around an atom will repel all other pairs, causing the pairs to take up positions as far apart as possible, to minimise the repulsion

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11
Q

What is the bond angle is a linear molecule

A

180

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12
Q

What is the bond angle in a trigonal planar molecule

A

120

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13
Q

What is the bond angle in a tetrahedral molecule

A

109.5

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14
Q

Bond angle in trigonal bipyramidal

A

120 and 90

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15
Q

Bond angle in Octahedral

A

90

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16
Q

What is special about molecules with lone pairs

A

the lone pairs repel more than bonded pairs

17
Q

Bond angle in trigonal pyramidal

A

107

18
Q

Bond angle in bent

A

104.5

19
Q

Structure breakdown

A

Ionic - giant, high melting point, conductive as a liquid and solution, but not solid

Giant covalent - high melting point, not conductive

Simple covalent - low melting point, not conductive

Metallic - high melting point, conductive