3 Atomic Structure and the Periodic Table Flashcards
The sum of an atom is the sum of its
neutrons and protons.
The atomic number is the same as the
number of protons.
Quantum Numbers:
Shells: n=
1,2,3. . .
Subshells: l =
0, 1, 2. . .
The angular momentum quantum number, or subshell, describes the shape of an electron’s orbital.
- The first shell (n=1) has one subshell s, or l = 0
- The 2nd shell (n=2) has two subshells: s (l=0), and p (l=1)
- The 3rd shell (n=3) has 3 subshells: s(l=0), p(l=1), d (l=2)
Orbitals: ml =
. . .-1, 0, 1. . .
ml = +-L
Spin: ms =
+1/2, -1/2
Each orbital can contain two electrons: one with a positive spin and one with a negative spin.
Diamagnetic elements have all of their electrons
spin paired. paramagnetism are not paired, and are more affected by magnetic fields.
Energy of an electron:
En =
-2.178 X 10-18 / N2 Joules
En= the energy of the electrons
n = the principle quantum number of the electron
(DELTA)E =
hv = hc / (lambda)
(Delta)E = energy change
h= plancks constant, 6.63 X 10-34 Joules-sec
v = frequency of the radiation
lambda = wevelength of the radiation
c = the speed of light, 3.00 X 108 m/sec (c = lambdaf)
The de Broglie equation
lambda =
h/mv
lambda = wavelengh associated with a particle
m= mass of particle
v = speed of the particle
mv = p = momentum of the particle
h=planck’s constant, 6.63 X 10 -34 Joule-Sec
Moving from left to right across the periodic table, atomic radius
decreases
Moving down a group, atomic radius
increases.
Cations(positively charged ions) are
smaller than atoms.
Anions (negatively charged ions) are
larger than atoms
Ionization energy
Energy required remove an electron from an atom