3 Flashcards

1
Q

Water pollution

A

Pollution of the aquatic environment means the introduction by humans, indirectly or directly, of substance or energy (heat) that result in negative effects to plant, animal or human health.

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2
Q

Briefly describe the main effects of water pollution

A

Effects can be summarised by this list. These do not occur in isolation
* Aesthetic: By the release of pollutants with high suspended solids. It looks unsightly, e.g., litter, discolouration and smells. The colour and turbidity (a measure of cloudiness) of the water.
* Temperature: usually, heat
* Deoxygenation: lack of oxygen in the water leading to damage to aquatic life
* Toxicity: acute or chronic toxicity, causing harm to aquatic or human life. This can be caused by the release of pathogens (in raw sewage, for example), heavy metals, radioactive materials
* Sublethal toxicity: such as endocrine disruption or changes in biodiversity
* Acidity/alkalinity: disturbance of the pH regime
* Eutrophication: nutrients or biodegradable organics giving rise to excessive growths of some organisms

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3
Q

cycle of water use

A

Raw water → Treatment →Use → Collection → Treatment → Disposal or recycle

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4
Q

There are effectively two strands to consider when we think about water and liquid pollution.

A

1.How do we ensure that water is safe for us to drink/use?
2.How do we treat any liquid effluent once it has left our homes/businesses?

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5
Q

1991 Water Industries Act

A

Sets out duties & powers of water providers regarding water supply, provision of sewerage services & consenting requirements for the receipt of trade effluent.

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6
Q

1991 Water Resources Act

A

Sets out duties & powers of the EA for water resource management, abstraction & impounding, the control of pollution of water resources & flood defence. Regulates water resources, water quality and pollution. Outlines the functions of the EA

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7
Q

Where can raw freshwater be extracted from and what are the main sources of contamination within each one?

A

Raw freshwater is abstracted from lakes, rivers or underground sources. The lakes and rivers can be classified as lowland or upland depending on their location.

Lowland water sources contain high levels of natural organic and inorganic matter from human activity and are more prone to pollution. Consequently, they receive the highest level of treatment.

Upland waters and reservoirs contain higher naturally occurring organic matter levels from decaying vegetation. This, in combination with iron, is why many upland rivers are brown. They can quite often contain contamination from field run-off.

Groundwater is usually low in organic matter and less vulnerable to microbiological and chemical contamination. However, they frequently contain high levels of inorganic substances from rocks through which the water percolates. In addition, the presence of nitrogen compounds indicates possible pollution.

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8
Q

DRINKING WATER STANDARDS

A
  • Organoleptic : These are parameters that are sensed by humans (by eyes, nose and throat)
  • Physicochemical:
  • Temperature
  • pH
  • Conductivity
  • Substances undesirable in excess
  • Nitrate - linked to blue baby syndrome
  • Ammonia
  • Toxic substances
    can be geological or from industrial pollution
  • Microbiological species
    Usually due to human & animal excreta
  • Minimum for softened water
  • Ca & Mg
  • scales boilers
  • hard water linked to reduced heart attacks
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9
Q

The treatment train will vary according to the requirements for the supply and the nature of the water source but will usually contain the following:

A
  • Pre-treatment
    o Screening
    o Storage
    o Equalisation
    o Aeration
  • Primary treatment
    o Coagulation and flocculation
    o sedimentation
  • Secondary treatment
    o Filtration
  • Disinfection
  • Advanced treatment
    o Activated carbon
    o Membrane processes
    o Fe and Mn removal
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10
Q

PRE-TREATMENT types

A
  • SCREENS: To remove the larger contaminants
  • STORAGE & EQUALISATION: Water storage is required to even out any supply variation. Water is generally stored in an open reservoir or tank. These vessels also act as a buffer if the water source becomes polluted. Storage allows solids to settle, so maintaining the storage and equalisation tanks is necessary to remove any silt build-up.
  • AERATION:
    This type of pre-treatment is common for groundwater. It is used to:
    ▪ Release excess H2S
    ▪ Release excess CO2
    ▪ Increase O2
    Aeration can be a simple mechanical process, such as allowing the water to fall over a series of cascades.
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11
Q

PRIMARY TREATMENT types

A

SEDIMENTATION
COAGULATION & FLOCCULATION

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12
Q

what is SEDIMENTATION, what are the key parameters and typical values in the design?

A

is solid-liquid separation using gravity to remove suspended solids. Sedimentation usually takes place in large rectangular or circular vessels.

The key parameters and typical values in the design are:
- Surface overflow rate ~20-35m3/day/m2
- Detention times ~2-8h
- Weir overflow rate ~ 150-300m3/day/m2

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13
Q

COAGULATION & FLOCCULATION,
The most common coagulants are, and their benefits:

A

Process to remove suspended solids by addition of chemical agent

The most common coagulants are:
- Aluminium sulphate (alum)
- Ferrous sulphate (ferric)
- Ferric chloride

Benefits
- Reduction in suspended solids
- Reduction in BOD5
- Removal of floating matter

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14
Q

SECONDARY TREATMENT – FILTRATION, what is the filtration medium?

A

The filtration medium used in secondary treatment is usually sand but can be other media such as coal. Slow sand filtration improves water’s appearance by removing solids and pathogens.

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15
Q

There are many classifications of filtration systems, and they include:

A
  • Gravity or pressure
  • Rapid, slow or variable filtration rates
  • Cake or depth filtration
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16
Q

DISINFECTION

A

Disinfection is required to kill or render harmless the remaining pathogens. Like coagulation and filtration, the other
treatments remove >90% of bacteria and viruses. However, to meet the standards set by the EU and WHO additional disinfection is required.

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17
Q

The requirements of a good disinfectant are:

A
  • Toxic to microorganisms at concentrations well below the toxic threshold to humans & higher animals
  • Fast rate of kill
  • Persistent enough to prevent the regrowth of organisms in the distribution system
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18
Q

Most common industrial disinfectants:

A

Chlorination
Chlorine dioxide
Chloramines
Ozone
UV radiation

19
Q

The purpose of advanced water treatment is to:

A
  • Take water treated by standard process and improve it to an exceptional quality required by a particular industry
  • To treat water for a specific chemical or microbiological contaminant
20
Q

advanced water treatment methods include:

A
  • Iron and manganese removal (water softening)
  • Ion exchange and inorganic absorption
  • Adsorption of organics
  • Membrane processes including reverse osmosis
21
Q

What are the main sources of wastewater?

A
  • Domestic
  • Industrial
  • Infiltration / inflow
  • Stormwater
22
Q

To whom does industry need to apply for a wastewater discharge permit?

A

The Environment Agency

23
Q

The waste-producing company will need to provide the Environment Agency and/or the water authority with information about the effluent discharge. The permit and consent document will commonly include:

A
  • Location of discharge & design of the outlet
  • Steps required to minimise the polluting effect of the discharge
  • Facilities to enable sampling
  • Nature, origin, composition, temperature, volume, rate of discharge, periods when discharge can take place
  • Making of returns
  • Recording & monitoring requirements
24
Q

The properties of interest for industrial effluent are:

A

▪ Suspended solids (mg/l)
▪ BOD (mg/l)
▪ COD (mg/l)
▪ pH
▪ Temperature
▪ Flowrate (normal operation, emergency operation, shut down)

25
Q

Trade effluent charges are based on the Mogden formula. This takes into account the following costs (as relevant):

A
  • collection
  • primary treatment
  • biological treatment
  • treatment and disposal into the sea
  • biological oxidation of settled sewage
  • treatment and disposal of primary sludge
26
Q

BOD is

A

The BOD is the biochemical (or biological) oxygen demand. It is a measure of the amount of dissolved oxygen used by bacteria in the degradation of organic matter.

BOD5 - the amount of dissolved oxygen used by bacteria to break down organic matter at 20°C in 5 days BODu - ultimate, arbitrarily set at 20 days, ~ 2  BOD5

27
Q

COD is

A

COD is chemical oxygen demand, and it measures the total organic carbon [except some aromatics {e.g. benzene} – not oxidised]. It determines the amount of oxygen needed to oxidise the organics chemically

Faster test, ~ 2 hrs

28
Q

PROCESS WATER QUALITY

A
  • Raw - fire water, cooling towers, washing down, cleaning
    ▪ Usually, no treatment for this water.
    ▪ If used for cooling water, may add a biocide or corrosion inhibitor
  • Potable - drinking, washing, cooking
  • Softened - removal of Ca & Mg
  • Demineralised - removal of all minerals
  • Ultra-pure - for pharmaceuticals, brewing, electronics
29
Q

To conserve water:

A

*Reduce consumption
*Process optimisation
*Recycle
*Dispose

30
Q

How do water companies work out the effluent charge?

A

They use the Mogden formula. (You do not need to remember the Mogden formula)

31
Q

What is the difference between BOD and COD?

A

BOD – Biochemical/biological oxygen demand. It is the amount of oxygen required to break down organic material over 5 or 20 days. It measures readily biodegradable organics.
COD – Chemical oxygen demand. It is the amount of oxygen needed to chemically oxidise ALL organic material. It is a faster test.

32
Q

What is coagulation and flocculation and what is it used for?

A

Suspended solids of very small particle size have negligible settling velocity and cannot be removed through simple sedimentation. Instead, a chemical coagulant (such as Al or Fe sulphate or ferric chloride) can be added to promote particle agglomeration. Most suspended solids are negatively charged, so they repulse each other and stay in suspension. Adding the coagulant destabilises the particles’ charge, so they become attracted, coagulate and then settle.
A chemical coagulant is added to the water, and for a brief period (20 to 60seconds), rapid mixing is carried out. This is carried out in tanks of varying designs to produce a micro-floc. Having produced a micro-floc, the objective is to create a floc of adequate size to settle. After the first rapid mixing, follows a gentler mixing stage for 20-60minutes to coagulate the flocs further. Finally, there is a settlement stage from which the solids are removed to leave the clarified water. The amount of coagulant required for the water is established by laboratory tests.
It is used for:
- Reduction in suspended solids
- Reduction in BOD5
- Removal of floating matter

33
Q

You work for a food manufacturer that produces an effluent with high suspended solids and high COD. Propose a treatment scheme to make this wastewater suitable for re-use within the process.

A

There is no single correct answer for this question. Students should describe and arrangement of pre-treatment, primary, secondary and tertiary treatment that they think is appropriate for this application to remove physical, biological and chemical contaminants. It is also beneficial to consider a waste to energy element as part of the solution.

34
Q

Describe the activated sludge process.

A

It consists of a tank full of waste liquid from primary treatment and a mass of micro-organisms. Air is bubbled into the tank to provide oxygen to the aerobic bacteria. The microbes decompose the organic material to CO2, H2O, some stable compounds and more micro-organisms. The production of organisms is relatively slow. When most of the organic material has been used up, the micro-organisms are separated from the liquid in a settling tank, sometimes called a secondary or final clarifier. The microbes remaining in the tank have no food, become hungry and are activated – hence the term activated sludge. The collected sludge is then recycled. This process is continuous, with continuous sludge pumping and clean water discharge. This process does produce more microbes than are required, so a portion of the activated sludge must be disposed of. This is one of the problematic aspects of wastewater treatment.

35
Q

WASTEWATER TREATMENT

A
  • Primary treatment:
    Screen
    Comminutor
    Grit chamber
    Settling tank
  • Secondary treatment:
    Trickle filter
    Activated sludge process
    aerobic digestion and anaerobic digestion
  • TERTIARY TREATMENT
36
Q

what is AEROBIC DIGESTION, and what are its advantages and disadvantages?

A

Similar to activated sludge process, The main objective of the process is to reduce the solids content.
Air bubbled through
High power usage

Advantages:
- stabilised end product humus
- low capital cost
- easy operation
- low odour
- non-explosive gas (CO2 and NH3)
Disadvantages
- high operational price for power and oxygen
- reduced performance in cold weather
- no methane
- difficult to dewater sludge

37
Q

what is anaerobic digestion

A

Used primarily for waste sludges and
high strength ’ wastes
Effluent quality not as good as that from
aerobic
Often used as a pretreatment to municipal
collection or aerobic treatment
Increasingly common in process plants to
reduce costs

38
Q

Anaerobic vs aerobic

A

ANEROBIC
Less energy required
Less nutrients required
Methane production
Smaller reactor volume
More sensitive to process upsets
Effluent does not meet discharge limits

AEROBIC
Produces odourless, stable humus
No explosion risk
Simple technology, low capital cost
High power usage
Low BOD concentration in final effluent

39
Q

TERTIARY TREATMENT meaning and types

A

Sometimes additional treatment is required to remove any remaining BOD and suspended solids. Neither primary nor secondary treatment is effective are removing phosphorous or toxic substances.

types:
Polishing pond
Oxidation pond
Carbon adsorption
Reverse osmosis

40
Q

Sludge treatment, Three issues with sludge:

A

A solid waste issue from liquid waste treatment!

Three issues with sludge:
1.Aesthetically displeasing
2.Potential harmful
3.High water content

41
Q

Sludge stabilisation

A

Lime stabilisation
Aerobic digestion
Anaerobic digestion

Aiming to deal with the pathogens
Reduce hazard and smell

42
Q

Sludge thickening:
Two types of non-mechanical thickener are in use:
what are The main reasons for thickening sludge before digestion?

A

TYPES:
- Gravity thickener
- Flotation thickener - air is forced under pressure into the line

The main reasons for thickening sludge before digestion are:
- To maximise the use of available digester capacity
- To prevent the dilution of the feed material
- To reduce the amount of heat required in a heated digester
- To avoid the washout of solids and micro-organisms
- To prevent pH instability

43
Q

what is SLUDGE DEWATERING

A

Dewatering is used as a final method of volume reduction before ultimate disposal. The dried sludge may also be turned into pellets used in thermal processes such as incineration or pyrolysis.

–Sand beds – have been used for many years and are very cost-effective when the land is available.
—Filtration - usually done using a pressure filter or a belt filter. This is a mechanical method for removing the water from the sludge.
—Centrifugation - This will work on any sludge.

44
Q

Sketch a sand filter bed and describe how it is cleaned.

A

Students should draw a simple diagram of a sand filter bed.
It is cleaned by reversing the flow of water through the sand, effectively washing all collected contaminants from the sand. The contaminated wash water may then we sent for clean up or disposal