2nd Year Liquids and Vapours/Entropy/Second Law Flashcards
Compressed Liquid =
Liquid below Tsat
Superheated Liquid =
Gas above Tsat
Wet Vapour
Mix of gas and liquid at Tsat
Dryness fraction
Quality can be found using interpolation between “Sat g” and “Sat f” values
V =
mv
Useful in questions
Can I use the perfect Gas Laws?
HELLA NO!
Second Law:
Entropy will always increase
Thermal efficiency =
W net / Qin
or
1 - Q(out)/Q(in)
Will always be less than 1
Calculte Entropy :
ΔS = Q/T
T in Kelvin!
What is entropy?
Referred to as “measure of chaos”
ΔS will always be positive
Zeroth Law:
If 2 systems are in equilibrium with a third, then they are also in equilibrium with eachother
Third Law:
Entropy of a perfect crystal at 0 Kelvin is 0.
Δs =
Cv Ln(T2/T1) + R Ln(V2/V1)
Cp Ln(T2/T1) - R ln(P2/P1)
Cp Ln(V2/V1) + Cv Ln (P2/P1)
These can be manipulated for easy equations at const T,P,V
Expansion Process
Isentropic Efficiency =
Actual Work out / Ideal Work out
Work Transfer decreases as Δs increases
Compression Process
Isentropic Efficiency =
Ideal Work in/ Actual Work in
Work consumed decreases as Δs increases
How to find q? (from T and S)
Area under a T-s Diagram
Remember T in Kelvin!