2nd lecture - orbitals Flashcards

1
Q

electrons can be described as

A

waves
particles

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2
Q

electrons have what duality

A

wave-particle duality

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3
Q

what can we not be sure of for wave/particles

A

position + momentum
more we know about one, the less we know about the other

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4
Q

why cant we know the position and momentum of an e-

A

when we look at it, the light energy being reflect off it changes the e- momentum due to the increase of energy from the light.

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5
Q

where are electrons found and why is it not in orbits

A

orbits: e- would have a precise position and path

e- are found in orbitals

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6
Q

what is an orbital

A

a region where the probability of finding an electron is high

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7
Q

what is a wave equation

A

an equation that describes a wave.

eg: sin equation will always give the same shape of wave.

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8
Q

what does the schrodinger equation tell u

A

how a particle behaves
where an e- is gonna go
probability distribution in space

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9
Q

what is the wavefunction

A

mathematical description of an e-

equivalent to the y axis on the sin wave

cannot be measured

amplitude of the equation at a given value when the schrodinger equation gives the wave

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10
Q

what do we use instead of psi (wave function)

A

wave function^2
gives a positive number

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11
Q

what is wavefunction^2

A

probability of finding an e- at xyz

useful in predicting how e- interact with other atoms in bonds

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12
Q

quantum number n

A

principle quantum number

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13
Q

what integers can n be

A

1
2
3
4 etc

not 0

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14
Q

what does the principle quantum number determine

A

size and energy of the orbital

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15
Q

what does a larger principle quantum number mean

A

its further away from the nucleus

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16
Q

quantum number l

A

azimuthal quantum number

17
Q

what does the l number represent

A

angular momentum quantum number

18
Q

what values can l be

A

0 and others
depends on n
can be any number up till n
n=2 l= 0,1

19
Q

what does the azimuthal quantum number l represent

A

determines the shape

20
Q

quantum number Ml

A

magnetic quantum number

21
Q

what integers can the magnetic quantum number be

A

positive and negative
l=2. Ml can be: -2,-1,0,1,2

22
Q

what does the magnetic quantum number determine

A

orientation of orbital relative to the Cartesian axis

23
Q

what do the quantum numbers add up to describe

A

orbitals
solutions to the schrodinger equation for the H atom
distribution of electrons

24
Q

name what azimuthal number corresponds to each orbital

A

0= s
1= p
2= d
3= f
4= g

25
Q

what is the 3p orbital in quantum numbers

A

n=3
l=1

26
Q

summary

A

orbitals are areas where there is a probability of finding an e-

schrodinger equation gives us orbitals

wavefunction is given by schrodinger

orbitals are described by quantum numbers: n, l, ml