2B Acids, Bases and Salts Flashcards
Brønsted-Lowry acid
A proton (H+ ion) donator
Strong acid
A strong acid dissociates fully so that all the ions have separated.
H3PO4(aq) —> 3H+(aq) + PO4 3- (aq)
Weak acid
A weal acid partially dissociates in solution
CH3CH2COOH (aq) ⇌ H+(aq) + CH3CH2COO- (aq)
Brønsted-Lowry base
A proton (H+ ion) acceptor
Alkali
a soluble base. Dissolves in water and gives off OH-
Metal hydroxide to form an Alkali
Mg(OH)2 (s) + aqua —> Mg2+ (aq) + 2OH- (aq)
Metal oxide to form an Alkali
CaO (s) + H2O (l) —> Ca2+ (aq) + 2OH- (aq)
Ammonia to form an Alkali
NH3 (g) + H2O (l) —> NH4+(aq) + OH- (aq)
Salt
The ionic compound formed when the H+ ions in an acid is replaced by positive metal ions or ammonium ions.
Charges of Gr 1, Gr 2 and Gr 3
Gr 1 = 1+
Gr 2 = 2+
Gr 3 = 3+
Charges of Gr 6, Gr 7 and Gr 8
Gr 6 = 2-
Gr 7 = 1-
Gr 8 = 0
Charges of Ag, Zn and NH4
Ag = 1+ Zn = 2+ NH4 = 1+
Charges of CO3, SO4, NO3, PO4, HCO3, OH
CO3 = 2- SO4 = 2- NO3 = 1- PO4 = 3- HCO3 = 1- OH = 1-
Acid + Metal hydroxide
Acid + Metal hydroxide —> Salt + Water
Acid + Metal carbonate
Acid + Metal carbonate —> Salt + Water + Carbon dioxide
Acid + Metal oxide
Acid + Metal oxide —> Salt + Water
Acid + Metal
Acid + Metal —> Salt + Hydrogen
Acid + Ammonia
Acid + Ammonia —> Ammonium Salt
Soluble ions
Gr. 1 ions Ammonium ions Nitrate ions Hydrogen carbonate ions Halides, except with Ag, Pb, and Hg Sulfates, except with Ag, Pb, Ca, Sr and Br
Insoluble ions
Oxide ions, except with Ca and Ba
Carbonate ions, except with Gr. 1, Ammonium ions
Phosphate ions, except with Gr. 1, Ammonium ions, Ca, Mg, Sr and Ba
Hydroxide ions, except with Gr. 1, Ammonium ions
Sulfide ions, except with Gr. 1, Ammonium ions
Dichromate, except with Gr. 1, Ammonium ions, Ca and Mg
d.p in mean titre
2 d.p
How close should result be in a mean
0.10 cm3
Identifying Halides
- Add silver nitrate solution and dilute nitric acid to the unknown solution and record observations
- Add dilute NH3 to unknown Ag halide and record observations
- Add concentrated NH3 to unknown Ag halide and record observations
Cl = white ppt, dissolves in dilute, dissolves in conc Br = cream ppt, insoluble in dilute, dissolves in conc I = yellow ppt, insoluble in dilute, insoluble in conc
Identifying sulphates
- Add barium nitrate
2. White precipitate should form
Carbonate ions
- Add dilute nitric acid to the unknown
- If carbonate ions are present, there should be effervesce
- Limewater should turn cloudy indicating CO2
test for Ammonium ions
- Add sodium hydroxide to the unknown
- Warm/ heat gently
- Test for ammonia gas (release of OH- ions) using damp red litmus paper which should turn blue
Order of Anion tests
- Carbonate test, sulfate + halide don’t give off gas
- Sulfate test, chloride gives of white ppt
- Halide test, the previous tests with rule. them out.