2.3 - Acid–base and redox reactions Flashcards
Name and write the formula of some common acids ?
- Hydrochloric acid (HCl )
- Nitric acid ( HNOv3 )
- Sulphuric acid ( Hv2SOv4 )
Name and write the formula of some common alkalis ?
- Sodium hydroxide ( NaOH )
- Potassium hydroxide ( KOH )
- Ammonia ( NHv3 )
What happens when an acid dissolved in water ?
When an acid dissolves in water it releases H+ ions forming an aqueous solution
What happens when an alkali dissolved in water ?
When an alkali dissolved in water it released OH- ions forming an aqueous solution
What is the difference between a strong and weak acid ?
- A strong acid is one that dissociates ( ionises ) completely when in water
- A weak acid is one that dissociates partially when in water
What is a neutralisation reaction ?
A neutralisation reaction where an acid and alkali react forming a salt and water
Write the ionic equation for a neutralisation reaction ?
OH-(aq) + H+(aq) —> Hv2O (l)
Write the equation for the following reaction : acid + alkali ?
Acid + alkali —> salt + water
Write the equation for the following reaction : Acid + metal carbonate ?
Acid + Metal carbonate —> salt + water + carbon dioxide
Describe what you would observe when a metal carbonate reacts with an acid ?
The solid/ metal carbonate would dissolve or disappear and there would be bubbling/ fizzing
Write the equation for the following reaction : Acid + Metal oxide ?
Acid + Metal oxide —> salt + water
Describe what you would observe when a metal oxide would react with an acid?
The solid/ metal oxide would dissolve or disappear
Do you know how to do calculations to find the concentration of an unknown solution ?
Yes
Define the term ‘oxidation’ ( both in terms of oxidation number and not ) ?
Oxidation - Oxidation is loss of electrons/ gain of oxygen and when the oxidation number of an element in an atom, molecule or ion increases
Define the term ‘reduction’ ( both in terms of oxidation number and not ) ?
Reduction - Reduction is the gain of electrons/ loss of oxygen and when the oxidation number of an element in an atom, molecule or ion decreases
What is a monoprotic acid ?
A proton donor that donates one H+ ( one proton )
What is a base ?
A proton acceptor, a substance that readily accepts H+ ions
What are diprotic and tripotic acids ?
- A diprotic acid is a proton donor which donates two H+ ions ( two protons )
- A triprotic acid is a proton donor which donates three H+ ions ( three protons )
Do you know how to use roman numerals to indicate the various oxidation number of elements in a compound ?
Yes
eg. Iron ( II ) chloride
Iron ( III ) chloride
What is oxidation number used for ?
Oxidation numbers are assigned to atoms to represent the relative ( in comparison to something else ) state of oxidation of the atom
What are the rules for assigning oxidation number ?
1 ) The oxidation number of all elements is ( 0 )
2 ) The oxidation number of ions are the same as their charges
3 ) Overall, oxidation number must equal zero in a compound, and equal the charge of any molecular ion
4 ) Roman numerals give the charge of an ion and oxidation number whether metallic/ non-metallic ( eg. Iron ( ll ) chloride = Fe2+ )
How can we determine whether something has been oxidised/ reduced using oxidation number ?
- A substance is oxidised when their oxidation number increases
- A substance is reduced when their oxidation number decreases
How do we balance using oxidation number ?
1 ) Assign oxidation numbers and then balance for any species that is oxidised or reduced
2 ) Now balance for electron transfer
3 ) Now finish by balancing other atoms checking charges on each side of the equation are the same
Can you use oxidation number to identify what substances have been oxidised/ reduced and whether it is a redox reaction ?
Yes
Can you balance an equation using oxidation number ?
Yes
What are the anomalies for oxidation number ?
- F always has an oxidation number of ( -1 )
- Hydrogen exists commonly as ( +1 ) but can exist as hydride ( H- ) with an oxidation number of ( -1 )
- Oxygen when in peroxides has an oxidation number of ( -1 )
What is a disproportionation reaction ?
A reaction in which a compound undergoes oxidation as well as reduction ( it both increases and decreases in oxidation number )