2.2 Flashcards

1
Q

orbital

A

region of space where an electron is likely to be found. it can hold 2 electron providing that they are of opposite spin

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2
Q

shape and number of s orbitals

A

spherical, 1 in every level

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3
Q

shape and number of p orbitals

A

dumbbell, 3 in levels 2 and up

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4
Q

number of d orbitals

A

5 in levels 3 and up

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5
Q

number of f orbital

A

7 in levels 4 and up

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6
Q

Aufbau principle

A

Electrons enter the lowest possible energy level

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7
Q

Rauls exclusion principle

A

2 electrons can go in each orbital provided they are of opposite spin

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8
Q

Hunds rule of maximum multiplicity

A

When in orbitals of equal energy electrons will try and remain unpaired

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9
Q

Types of intermolecular forces/ physical forces

A

Induced dipole- dipole interaction
Permanent dipole - dipole interaction
Hydrogen bonds

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10
Q

Ionic compounds

A

Formed between metals and non metals
Electrons are transferred
Giant ionic lattice , very brittle -> dislocation of layers leads to repulsion between similar ions, conduct electricity in solution or molten, soluble in polar solvents vv high melting point

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11
Q

Covalent bond

A

Shared pair of electrons with one electron being supplied by each atom on either side of the bond

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12
Q

Dative covalent bond

A

Shared pair of electrons where both electrons are donated by one atom

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13
Q

Why are covalent bonds strong

A

Electrostatic forces between the shared electrons and the positive nuclei

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14
Q

Properties of simple covalent molecules

A

Don’t conduct electricity
Low meting and boiling points due to weak intermolecular forces between molecules soluble in organic solvents but not in water

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15
Q

Lone pair

A

Pair of non bonded electrons

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16
Q

properties of giant covalent molecules

A

Don’t conduct electricity, very high melting and boiling points due to strong covalent bonds, in graphite delocalised electrons conduct electrons

17
Q

why do molecules form certain shapes

A

the shaped adopted by a simple ion or molecule it that which keeps the repulsive forces to a minimum

18
Q

shape and bond angles of a molecule with 2 bonded pairs

A

180 degrees, linear

19
Q

shape and bond angles of a molecule with 3 bonded pairs

A

120 degrees, trigonal planar

20
Q

shape and bond angles of a molecule with 4 bonded pairs

A

109.5, tetarhedral

21
Q

shape and bond angles of a molecule with 5 bonded pairs

A

120 and 90 trigonal bi-pyramidal

22
Q

shape and bond angles of a molecule with 6 boned pairs

A

90 octahedral

23
Q

by how much does a lone pair reduce a bond angle

A

2.5 degrees

24
Q

electronegativity

A

the ability of an atom to attract the pair or electrons in a covalent bond to itself

25
physical forces
the forces between different molecules within a substance (inter-molecular forces)
26
induced dipole dipole interaction explanation
at any point in time it is possible that the electrons in a molecule are on one side, an instantaneous dipole is produced inducing a weak dipole in nearby molecules creating weak forces between them
27
hydrogen boding
strongest type of intermolecular force. water is very polar-> very strong dipole dipole attraction called a hydrogen bond. h2o can from 2 hydrogen bonds
28
unusual properties of water
higher melting and boiling point than expected, ice is less dense than water so it floats, high surface tension and viscosity
29
why is ice less dense than water
when ice forms molecules form an open lattice keeping the molecules farther apart than when they are liquid
30
why does water have a higher melting/boiling point than expected
the very strong hydrogen bonds between the H2O molecules are much stronger than normal intermolecular forces.
31
why does water have a high surface tension and viscosity
the hydrogen bonds are stronger than normal intermolecular forces
32
permanent dipole dipole interaction
polar molecules are held together by dipole dipole interactions that occur between the oppositely charged dipoles
33
2 elements with different electron configuration
Chromium and copper, 4s fills before 3d because it's more stable